公开(公告)号：US08148312B2

公开(公告)日：2012-04-03

申请号：US13237817

申请日：2011-09-20

Applicant: Thomas W. Kaaret ,  Darin K. Griffith ,  Klein A. Rodrigues ,  William L. Smith

Inventor： Thomas W. Kaaret ,  Darin K. Griffith ,  Klein A. Rodrigues ,  William L. Smith

IPC: C11D3/02 ,  C11D3/37

CPC classification number: C08F2/18 ,  C08F8/44 ,  C08F212/08 ,  C08F220/06 ,  C08F2800/20 ,  C11D3/3757 ,  C11D3/3765 ,  C11D3/3956 ,  C11D3/42 ,  C08F2/44

Abstract: The invention provides an aqueous bleaching solution for substrate treatment comprising a source of oxidant and a suspended polymer matrix having a plurality of optically functional particles associated with one or more copolymers present in the polymer matrix. The plurality of optically functional particles are associated with the copolymer during polymerization of at least one hydrophobic and at least one hydrophilic monomer so as to form a polymer matrix useful to impart an aqueous bleaching solution with optically functional properties providing a benefit to the solutions during storage, use and application to substrates for treatment. In accordance with various embodiments of the invention, the suspended polymer matrix forms a substantially stable dispersion of the optically functional particles in the aqueous bleaching solution, and provides compositions, methods and kits for employing aqueous bleaching solutions having optically functional properties that are maintained over substantially long storage times.

Abstract translation: 本发明提供了用于底物处理的水性漂白溶液，其包括氧化剂源和悬浮聚合物基质，其具有与存在于聚合物基质中的一种或多种共聚物相关联的多个光学功能性颗粒。 在至少一种疏水性和至少一种亲水性单体的聚合过程中，多种光学功能性颗粒与共聚物相关联，以便形成聚合物基质，其可用于赋予具有光学功能性质的水性漂白溶液以提供储存期间的溶液的益处 ，使用和应用于底物进行治疗。 根据本发明的各种实施方案，悬浮聚合物基质形成水性漂白溶液中的光学功能性颗粒的基本上稳定的分散体，并且提供了使用具有光学功能特性的水性漂白溶液的组合物，方法和试剂盒， 长存储时间。

公开(公告)号：US07875359B2

公开(公告)日：2011-01-25

申请号：US11035160

申请日：2005-01-13

Applicant: Klein A. Rodrigues ,  Darin K. Griffith

Inventor： Klein A. Rodrigues ,  Darin K. Griffith

IPC: B32B27/30 ,  B32B27/00 ,  C08F120/00

CPC classification number: C08F220/06 ,  C08F2/18 ,  C08F8/44 ,  C11D3/3757 ,  Y10T428/3162 ,  Y10T428/3163 ,  Y10T428/31692 ,  Y10T428/31855

Abstract: A self-stabilizing dispersion composition having a copolymer having at least one polymerizable acid-containing moiety, wherein the at least one acid-containing moiety is at least partially neutralized before or during polymerization, and at least one hydrophobic moiety. A process for producing such compositions is also provided, as well as a process for encapsulating water-insoluble actives in such copolymers.

Abstract translation: 一种自稳定分散体组合物，其具有含至少一个含可聚合酸的部分的共聚物，其中所述至少一个含酸部分在聚合之前或期间至少部分中和，以及至少一个疏水部分。 还提供了一种制备这种组合物的方法，以及一种将水不溶性活性物质包封在这种共聚物中的方法。

公开(公告)号：US07799421B2

公开(公告)日：2010-09-21

申请号：US10074522

申请日：2002-02-14

Applicant: Susanne H. Goodson ,  Klein A. Rodrigues

Inventor： Susanne H. Goodson ,  Klein A. Rodrigues

IPC: B32B17/10 ,  A01K1/015 ,  A61Q5/08

CPC classification number: C11D3/3723 ,  C08J5/18 ,  C11D17/0039 ,  Y10T428/249921 ,  Y10T428/263 ,  Y10T428/269

Abstract: The invention relates to polymers whose water solubility may be triggered by changes in pH, salt concentration, concentration of surfactant or a combination of both. The polymer is a copolymer or terpolymer containing from 2 to 60 mole percent of an amine functionality that has been neutralized with a fixed acid. Specifically films formed from these polymers will be insoluble at a higher pH, but will become soluble at a lower pH. The polymers are also insoluble at a higher salt concentration, but become soluble at a lower salt concentration. The polymers can be used to coat or encapsulate active ingredients, that are released based on changes in the environment, such as in the rinse cycle of a dishwasher or laundry washing machine.

公开(公告)号：US20080221005A1

公开(公告)日：2008-09-11

申请号：US12013576

申请日：2008-01-14

Applicant: Thomas W. Kaaret ,  Darin K. Griffith ,  Klein A. Rodrigues ,  William L. Smith

Inventor： Thomas W. Kaaret ,  Darin K. Griffith ,  Klein A. Rodrigues ,  William L. Smith

IPC: C11D3/02 ,  C11D3/37

CPC classification number: C08F2/18 ,  C08F8/44 ,  C08F212/08 ,  C08F220/06 ,  C08F2800/20 ,  C11D3/3757 ,  C11D3/3765 ,  C11D3/3956 ,  C11D3/42 ,  C08F2/44

Abstract: The invention provides an aqueous bleaching solution for substrate treatment comprising a source of oxidant and a suspended polymer matrix having a plurality of optically functional particles associated with one or more copolymers present in the polymer matrix. The plurality of optically functional particles are associated with the copolymer during polymerization of at least one hydrophobic and at least one hydrophilic monomer so as to form a polymer matrix useful to impart an aqueous bleaching solution with optically functional properties providing a benefit to the solutions during storage, use and application to substrates for treatment. In accordance with various embodiments of the invention, the suspended polymer matrix forms a substantially stable dispersion of the optically functional particles in the aqueous bleaching solution, and provides compositions, methods and kits for employing aqueous bleaching solutions having optically functional properties that are maintained over substantially long storage times.

Abstract translation: 本发明提供了用于底物处理的水性漂白溶液，其包括氧化剂源和悬浮聚合物基质，其具有与存在于聚合物基质中的一种或多种共聚物相关联的多个光学功能性颗粒。 在至少一种疏水性和至少一种亲水性单体的聚合过程中，多种光学功能性颗粒与共聚物相关联，以便形成聚合物基质，其可用于赋予具有光学功能性质的水性漂白溶液以提供储存期间的溶液的益处 ，使用和应用于底物进行治疗。 根据本发明的各种实施方案，悬浮聚合物基质形成水性漂白溶液中的光学功能性颗粒的基本上稳定的分散体，并且提供了使用具有光学功能特性的水性漂白溶液的组合物，方法和试剂盒， 长存储时间。

公开(公告)号：US06500212B1

公开(公告)日：2002-12-31

申请号：US09708133

申请日：2000-11-08

Applicant: Klein A. Rodrigues ,  Susanne Goodson

Inventor： Klein A. Rodrigues ,  Susanne Goodson

IPC: D06M13322

CPC classification number: C11D3/32 ,  C11D3/0015 ,  C11D3/323 ,  D06M13/419 ,  D06M13/432 ,  D06M2200/20 ,  D06M2200/50

Abstract: The present invention is directed to a method for treating a material to impart wrinkle reduction and temporary crease resistance thereto, and improve feel. The method involves: applying to said material a solution of a treatment composition in an amount effective to impart temporary crease and stain resistance, said fabric treatment composition comprising a hydroxy urea or hydroxy amide compound; and allowing said treatment composition to dry at ambient temperature, wherein said hydroxy urea compound comprises one urea and at least one hydroxyl group and said hydroxy amide compound comprises at least one amide group and at least one hydroxyl group. The material treatment is useful in reducing wrinkles in clothing, improving the feel of fabrics, and increasing the moisture adsorbence and retention in natural and synthetic fabrics.

Abstract translation: 本发明涉及一种用于处理材料以赋予皱纹减少和临时抗皱性的方法，并且改善感觉。 所述方法包括：将所述处理组合物的溶液以有效赋予临时皱纹和抗污染性的量施用于所述材料，所述织物处理组合物包含羟基脲或羟基酰胺化合物; 并使所述处理组合物在环境温度下干燥，其中所述羟基脲化合物包含一个脲和至少一个羟基，并且所述羟基酰胺化合物包含至少一个酰胺基和至少一个羟基。 材料处理可用于减少衣服的皱纹，改善织物的感觉，以及增加天然和合成织物中的水分吸附和保留。

公开(公告)号：US06458752B1

公开(公告)日：2002-10-01

申请号：US09274838

申请日：1999-03-23

Applicant: Klein A. Rodrigues

Inventor： Klein A. Rodrigues

IPC: C11D337

CPC classification number: C11D3/378 ,  C11D3/3761 ,  C11D3/3784 ,  C11D17/06

Abstract: A powder detergent composition which exhibits improved soil suspending properties on organic non-polar and polar soils in wash liquors. The powder detergent comprises a water-soluble or water-dispersible polymer having pendant acid functionality and a terminal fragment of a chain transfer agent, wherein the polymer is the polymerization product of a ethylenically unsaturated acid monomer and a C1 to C24 chain transfer agent. The polymers also boost the cleaning performance of hard surface and dishware detergent compositions.

Abstract translation: 一种粉末洗涤剂组合物，其在洗涤液中的有机非极性和极性污垢上表现出改善的污垢悬浮性能。 粉末洗涤剂包括具有侧链酸官能团的水溶性或水分散性聚合物和链转移剂的末端片段，其中聚合物是烯属不饱和酸单体和C1至C24链转移剂的聚合产物。 聚合物还提高了硬表面和餐具洗涤剂组合物的清洁性能。

公开(公告)号：US06384166B1

公开(公告)日：2002-05-07

申请号：US09714645

申请日：2000-11-16

Applicant: Anne-Marie Austin ,  Allen M. Carrier ,  Klein A. Rodrigues

Inventor： Anne-Marie Austin ,  Allen M. Carrier ,  Klein A. Rodrigues

IPC: C08F22802

CPC classification number: C08F222/02

Abstract: A low color or colorless polymaleate as determined by a Gardner color number of 8 or less, said polymaleate is prepared by aqueous solution polymerization of 70 to 99.9 weight percent of maleic acid, 0.1 to 30 weight percent of an allylic sulfonate monomer, and 0.5 to 50 &mgr;m, based on the moles of monomer, of a polyvalent transition metal ion selected from group consisting of Group IVA, VA, VIA, VIIA, VIIIA, IB, IIB, and combinations thereof, wherein the weight percents are based on the total weight of monomer, provided that 10 to 60 mole percent of the carboxylic acid groups on the maleic acid are neutralized prior to polymerization. The low color or colorless polymaleates provide permanent press properties to textiles treated therewith and increases the resistance of such textiles to laundering abrasion. The polymaleates also may be used in cleaning compositions to disperse and suspend soils.

公开(公告)号：US06306815B1

公开(公告)日：2001-10-23

申请号：US09393117

申请日：1999-09-10

Applicant: Klein A. Rodrigues ,  John S. Thomaides

Inventor： Klein A. Rodrigues ,  John S. Thomaides

IPC: C11D337

CPC classification number: C11D3/0021 ,  C08F26/06 ,  C11D3/3776

Abstract: A water-soluble quaternary polyvinylpyrridinium derivative which inhibits dye transfer in detergent compositions without adversely affecting stain or soil removal or soil redeposition. The quaternary polyvinylpyrridinium derivative contains a quaternary nitrogen and an anionic moiety selected from a sulfonate and/or a carboxylate functionality, said quaternary polyvinylpyrridinium derivative having the structure

Abstract translation: 一种水溶性季节聚乙烯基吡啶鎓衍生物，其抑制洗涤剂组合物中的染料转移而不会不利地影响污点或污垢去除或污垢再沉积。 季聚乙烯基吡啶鎓衍生物含有季氮和选自磺酸盐和/或羧酸官能团的阴离子部分，所述季聚乙烯基吡啶鎓衍生物具有结构

公开(公告)号：US06191098B1

公开(公告)日：2001-02-20

申请号：US09300913

申请日：1999-04-28

Applicant: Klein A. Rodrigues ,  John S. Thomaides

Inventor： Klein A. Rodrigues ,  John S. Thomaides

IPC: C11D337

CPC classification number: C11D3/3776 ,  C08F8/00 ,  C08F8/44 ,  C11D3/0036 ,  C08F8/34 ,  C08F26/06 ,  C08F8/30 ,  C08F126/06 ,  C08F220/20

Abstract: A water-soluble polyvinylpyrridinium derivative containing a quaternary nitrogen and an anionic moiety selected from a sulfonate and/or a carboxylate functionality, said polyvinylpyrridinium derivative having the structure wherein a is a repeating unit of 1 to 100; b is a repeating unit of 0 to 99; c is a repeating unit of 0 to 99; d is a repeating unit of 0 to 99; R is selected from the group consisting of (CR1R2)m1, benzene, and substituted benzene; Y is selected from the group consisting of (CR3R4)m2, benzene, and substituted benzene; substituted benzene is independently a benzene substituted with a group selected from the group consisting of amino moeity, nitro moiety, halogen moiety, and combinations thereof; Z is derived from an ethylenically unsaturated monomer; m1 and m2 are independently 0 to 10; M+ is independently a cation wherein M is selected from the group consisting of hydrogen, ammonia, alkali metals, alkaline earth metals, zinc, copper, organic amines, amino acids, and amino saccharides; R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, hydroxyl, alkyl having C1 to C6, aryl having C6 to C18, and alkaryl having C7 to C18; and X− is independently a halide, with the proviso that if Y is benzene or substituted benzene then a is 0 to 99 and b is 1 to 100. The polyvinylpyrridinium derivatives inhibit dye transfer in detergent compositions having a high level of anionic surfactants without adversely affecting stain or soil removal or soil redeposition.

Abstract translation: 含有季氮和选自磺酸酯和/或羧酸酯官能团的阴离子部分的水溶性聚乙烯基吡啶鎓衍生物，其中a所示结构的聚乙烯吡啶鎓衍生物为1〜100重复单元; b为0〜99的重复单元; c为0〜99的重复单元; d为0〜99的重复单元; R选自（CR 1 R 2）m1，苯和取代的苯; Y选自（CR 3 R 4）m 2，苯和取代的苯; 取代苯独立地是被选自氨基甲酰基，硝基部分，卤素部分及其组合的基团取代的苯; Z衍生自烯属不饱和单体; m1和m2独立地为0至10; M +独立地是阳离子，其中M选自氢，氨，碱金属，碱土金属，锌，铜，有机胺，氨基酸和氨基糖; R1，R2，R3和R4独立地选自氢，羟基，具有C1至C6的烷基，具有C6至C18的芳基和具有C7至C18的烷芳基; X是独立的卤化物，条件是如果Y是苯或取代的苯，那么a是0到99，b是1到100.聚乙烯基吡啶鎓衍生物抑制染料在具有高含量阴离子表面活性剂的洗涤剂组合物中的转移 影响污渍或污垢去除或土壤再沉积。

公开(公告)号：US5368642A

公开(公告)日：1994-11-29

申请号：US109744

申请日：1993-08-20

Applicant: Klein A. Rodrigues ,  Larry S. Eoff

Inventor： Klein A. Rodrigues ,  Larry S. Eoff

IPC: C04B24/00 ,  C04B24/12 ,  C09K8/46

CPC classification number: C04B24/121 ,  C04B24/003 ,  C04B24/123 ,  C09K8/46 ,  C04B2103/22

Abstract: A functionalized polyamine effective to retard the setting rate of a slurry of hydraulic cement is disclosed. A slurry of hydraulic cement in water which includes the functionalized polyamine, which is a polyethylene amine having attached thereto moieties selected from the group consisting of carboxylic acid groups and phosphonic acid groups, is useful to cement a conduit in a subterranean formation penetrated by a wellbore wherein it is desirable to retard the setting rate of the cement to enable placement of the slurry.

Abstract translation: 公开了一种有效阻止水硬性水泥浆料凝固速率的官能化多胺。 包括官能化多胺（其中连接有选自羧酸基团和膦酸基团的部分的聚乙烯胺）的水硬性水泥浆体可用于在穿透井筒的地下地层中的管道上水泥 其中期望延迟粘合剂的凝固速率以使浆料能够放置。