公开(公告)号：US08664131B2

公开(公告)日：2014-03-04

申请号：US13933600

申请日：2013-07-02

Applicant: Corning Incorporated

Inventor： George Halsey Beall ,  Marie Jacqueline Monique Comte ,  George Owen Dale ,  Linda Ruth Pinckney ,  Charlene Marie Smith ,  Ronald Leroy Stewart ,  Steven Alvin Tietje

IPC: C03C10/04 ,  C03C10/10 ,  C03C10/12

CPC classification number: C03C14/006 ,  C03B20/00 ,  C03B32/02 ,  C03C3/085 ,  C03C3/093 ,  C03C10/0009 ,  C03C10/0027 ,  C03C14/00 ,  C03C21/002 ,  Y10T428/315

Abstract: Crystallizable glasses, glass-ceramics, IXable glass-ceramics, and IX glass-ceramics are disclosed. The glass-ceramics exhibit β-spodumene ss as the predominant crystalline phase. These glasses and glass-ceramics, in mole %, include: 62-75 SiO2; 10.5-17 Al2O3; 5-13 Li3O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; and 0.05-0.2 SnO2. Additionally, these glasses and glass-ceramics exhibit the following criteria: a. a ratio: [ Li 2 ⁢ O + Na 2 ⁢ O + K 2 ⁢ O + MgO + ZnO _ ] ⁢ [ Al 2 ⁢ O 3 + B 2 ⁢ O 3 ] between 0.7 to 1.5; b. a ratio: [ TiO 2 + SnO 2 _ ] ⁢ [ SiO 2 + B 2 ⁢ O 3 ] greater than 0.04. Furthermore, the glass-ceramics exhibit an opacity ≧about 85% over the wavelength range of 400-700 nm for an about 0.8 mm thickness and colors an observer angle of 10° and a CIE illuminant F02 determined with specular reflectance included of a* between −3 and +3, b* between −6 and +6, and L* between 88 and 97.

Abstract translation: 公开了可结晶玻璃，玻璃陶瓷，IXable玻璃陶瓷和IX玻璃陶瓷。 玻璃陶瓷显示出β-锂辉石为主要结晶相。 这些玻璃和玻璃陶瓷（摩尔％）包括：62-75SiO 2; 10.5-17 Al2O3; 5-13 Li3O; 0-4 ZnO; 0-8 MgO; 2-5 TiO2; 0-4 B2O3; 0-5 Na2O; 0-4 K2O; 0-2 ZrO2; 0-7 P2O5; 0-0.3 Fe2O3; 0-2 MnOx; 和0.05-0.2 SnO2。 另外，这些玻璃和玻璃陶瓷具有以下标准：a。 比例：0.7〜1.5的[Li 2 O + Na 2 O + K 2 O + MgO + ZnO]] [Al 2 O 3 + B 2 O 3] b。 比例：[TiO 2 + SnO 2]] [SiO 2 + B 2 O 3]大于0.04。 此外，玻璃陶瓷在400-700nm的波长范围内表现出大约85％的不透明度，约0.8mm厚度，并且观察角度为10°，CIE光源F02由包含a * 在-3和+3之间，b *在-6和+6之间，L *在88和97之间。