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公开(公告)号：US20130050367A1
公开(公告)日：2013-02-28
申请号：US13695099
申请日：2011-06-08
申请人： Ivan Hoogmartens
发明人： Ivan Hoogmartens
CPC分类号： C09D11/32 , B41J2/2107 , C09D11/101
摘要： A free radical radiation curable inkjet ink containing a photoinitiator and polymerizable compounds includes at least 45 wt % of a mixture of monomers consisting of: a) 10 to 35 wt % of one or more cyclic monofunctional acrylates wherein the homopolymer thereof has a Tg larger than 20° C.; b) 10 to 30 wt % of a N-vinyl lactam and/or a vinylether acrylate; c) 10 to 30 wt % of an ethoxylated and/or propoxylated polyacrylate having a molecular weight of at least 450; wherein all wt % are based on the total weight of the inkjet ink; and wherein the Tg is determined by the DSC method in ISO 11357-2:1999.
摘要翻译： 含有光引发剂和可聚合化合物的自由基可辐射固化喷墨油墨包括至少45重量％的由以下组成的单体混合物的混合物：a）10至35重量％的一种或多种环状单官能丙烯酸酯，其中其均聚物的Tg大于 20°C。 b）10〜30重量％的N-乙烯基内酰胺和/或乙烯基醚丙烯酸酯; c）10至30重量％的分子量至少为450的乙氧基化和/或丙氧基化聚丙烯酸酯; 其中所有wt％都是基于喷墨油墨的总重量; 并且其中Tg通过ISO 11357-2：1999中的DSC方法测定。
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公开(公告)号：US20100047455A1
公开(公告)日：2010-02-25
申请号：US12299312
申请日：2007-05-10
申请人： Ivan Hoogmartens
发明人： Ivan Hoogmartens
IPC分类号： B05D1/36 , C08K5/3415 , C08K7/00
CPC分类号： C09D11/40 , C09D11/322 , C09D11/36
摘要： A non-aqueous inkjet ink includes a diketopyrrolo-pyrrole pigment and at least one polyalkyleneglycol dialkylether having a molecular weight of at least 250. Also, a method for manufacturing decorative laminates using the non-aqueous inkjet ink is provided.
摘要翻译： 非水性喷墨油墨包括二酮吡咯并 - 吡咯颜料和分子量至少为250的至少一种聚亚烷基二醇二烷基醚。另外，提供了一种使用非水性喷墨油墨制造装饰层压板的方法。
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公开(公告)号：US20100029813A1
公开(公告)日：2010-02-04
申请号：US12441725
申请日：2007-10-01
IPC分类号： C09D11/10
CPC分类号： C09D11/101
摘要： A non-aqueous inkjet ink includes a benzimidazolone pigment and a polymeric dispersant according to Formula (I): wherein, T represents hydrogen or a polymerization terminating group; Z represents the residue of polyethyleneimine having a number-average molecular weight of at least 100; A represents an oxyalkylene carbonyl group; T-C(O)An- represents a TPOAC-chain which is bound to Z through an amide bond; and n and m are integers wherein m is at least 2 and n is from 2 to 100; the polymeric dispersant fulfills the conditions of: WTPOAC>57 and NAmide≧65 mol % wherein WTPOAC represents the ratio of the weight percentage of TPOAC-chains over the weight percentage of amide bonds in the polymeric dispersant; NAmide represents the mol % of amide bonds based on the total nitrogen content of the polymeric dispersant; and the values of WTPOAC and NAmide are calculated from the total nitrogen content determined by dry combustion of the polymeric dispersant and from the amine content determined through potentiometric titration in a mixture of CH3COOH:THF (14.5:0.5) with 0.1N aqueous perchloric acid.
摘要翻译： 非水性喷墨油墨包括苯并咪唑酮颜料和根据式（I）的聚合物分散剂：其中T表示氢或聚合终止基团; Z表示数均分子量为100以上的聚乙烯亚胺的残基; A表示氧化烯羰基; T-C（O）An-表示通过酰胺键与Z结合的TPOAC-链; 并且n和m是其中m为至少2且n为2至100的整数; 聚合物分散剂满足以下条件：WTPOAC> 57和NAmide> = 65mol％，其中WTPOAC表示TPOAC链的重量百分比与聚合物分散剂中酰胺键的重量百分比的比率; 基于聚合物分散剂的总氮含量，NAmide表示酰胺键的摩尔％; 并且从通过聚合物分散剂的干燃烧确定的总氮含量和通过在CH 3 COOH:THF（14.5:0.5）与0.1N高氯酸的混合物中的电位滴定测定的胺含量计算WTPOAC和NAmide的值。
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公开(公告)号：US07172852B2
公开(公告)日：2007-02-06
申请号：US11204690
申请日：2005-08-16
CPC分类号： G03C1/005 , G03C1/498 , G03C1/49827 , G03C1/49845 , G03C1/4989 , G03C7/3041 , G03C2001/03588 , G03C2001/03594 , G03C2001/091 , G03C2001/7448 , G03C2200/16 , Y10S430/165 , Y10S430/166
摘要： A black and white thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing at least one substantially light-insensitive organic silver salt, a binder and optionally photosensitive silver halide, characterized in that the thermosensitive element further contains deliberately added metal nano-particles in a molar ratio with respect to the total molar concentration of the at least one substantially light-insensitive organic silver salt in the range of 0.05:1 to 10−6:1; and the use for the purpose of increasing the ratio of Dmax to the quantity of said substantially light-insensitive organic silver salts per unit area of the above-mentioned thermographic recording material.
摘要翻译： 包含热敏元件和载体的黑色和白色温度记录材料，所述热敏元件含有至少一种基本上不受光敏的有机银盐，粘合剂和任选的感光卤化银，其特征在于，所述热敏元件还包含有意添加的金属纳米 相对于至少一种基本上不光敏感的有机银盐的总摩尔浓度的摩尔比在0.05:1至10-6:1范围内的颗粒; 以及用于将上述热敏记录材料的每单位面积中的D max max与所述基本上不受光敏感的有机银盐的比例增加的目的的用途。
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公开(公告)号：US06774084B2
公开(公告)日：2004-08-10
申请号：US10106172
申请日：2002-03-26
申请人： Johan Loccufier , Geert Defieuw , Ivan Hoogmartens
发明人： Johan Loccufier , Geert Defieuw , Ivan Hoogmartens
IPC分类号： B41M530
CPC分类号： G03C1/4989 , G03C1/49827 , G03C1/49845
摘要： A monosheet black and white substantially light-insensitive thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing a substantially light-insensitive organic silver salt, a 1,2-dihydroxyphenyl-compound in thermal working relationship therewith and a binder, wherein said 1,2-dihydroxyphenyl-compound is represented by formula (I): R1SO2R2, wherein R1 is an optionally substituted aryl group and R2 is selected from the group consisting of a 3,4,5-trihydroxyphenyl group, a 3-alkoxy-4,5-dihydroxyphenyl group and a 3-aryloxy-4,5-dihydroxyphenyl group; or said 1,2-dihydroxyphenyl-compound is represented by formula (II): R3COOR4, wherein R3 is a 3-alkoxy-4,5-dihydroxyphenyl group or a 3-aryloxy-4,5-dihydroxyphenyl group; and R4 is an alkyl group or an aryl group; and a thermographic recording process therefor.
摘要翻译： 包含热敏元件和载体的单片黑色和白色基本上不光敏感的热敏成像记录材料，所述热敏元件含有基本上不光敏的有机银盐，与其热处理的1,2-二羟基苯基化合物和粘合剂， 其中所述1,2-二羟基苯基化合物由式（I）表示：R 1 SO 2 R 2，其中R 1是任选取代的芳基，R 2选自 3,4,5-三羟基苯基，3-烷氧基-4,5-二羟基苯基和3-芳氧基-4,5-二羟基苯基; 或所述1,2-二羟基苯基化合物由式（II）表示：R 3 COOR 4，其中R 3为3-烷氧基-4,5-二羟基苯基或3-芳氧基-4 ，5-二羟基苯基; 和R 4是烷基或芳基; 及其热成像记录方法。
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公开(公告)号：US06300052B1
公开(公告)日：2001-10-09
申请号：US09138048
申请日：1998-08-21
申请人： Frank Louwet , Huub Van Aert , Frank Ruttens , Ivan Hoogmartens
发明人： Frank Louwet , Huub Van Aert , Frank Ruttens , Ivan Hoogmartens
IPC分类号： G03C1498
CPC分类号： G03C1/49863 , G03C1/4989
摘要： A substantially light-insensitive black and white thermographic material comprising a support and a thermosensitive element containing a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith and a binder, wherein the binder is a water-dispersible film-forming polymer having covalently bonded ionic groups and the thermographic material is thermally developable under substantially water-free conditions; and a process for producing the substantially light-insensitive black and white thermographic material comprising the steps of: producing an aqueous dispersion of the substantially light-insensitive organic silver salt; producing one or more aqueous coating compositions containing together the aqueous dispersion of the substantially light-insensitive organic silver salt, the reducing agent and the binder; and applying the one or more aqueous coating compositions to the support, thereby forming after drying the thermosensitive element.
摘要翻译： 一种基本上不透光的黑色和白色热成像材料，其包括载体和含有基本上不光敏的有机银盐的热敏元件，与其热加工关系的还原剂和粘合剂，其中所述粘合剂是水分散性膜 - 具有共价键离子基团的成型聚合物，并且热成像材料在基本上无水条件下是可热显影的; 以及用于生产基本上不透光的黑白热成像材料的方法，包括以下步骤：制备基本上不光敏的有机银盐的水分散体; 制备一种或多种含有基本上不光敏的有机银盐，还原剂和粘合剂的水性分散体的水性涂料组合物; 并将一种或多种水性涂料组合物施加到载体上，从而在干燥热敏元件之后形成。
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17.发明授权
公开(公告)号：US6010843A
公开(公告)日：2000-01-04
申请号：US889485
申请日：1997-07-08
申请人： Ivan Hoogmartens , Hans Strijckers , David Terrell
发明人： Ivan Hoogmartens , Hans Strijckers , David Terrell
IPC分类号： G03C1/498
CPC分类号： G03C1/49836
摘要： A photothermographic recording material comprising a support and a photo-addressable thermally developable element containing a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith, photosensitive silver halide spectrally sensitized with a dye and in catalytic association with the substantially light-insensitive organic silver salt and a binder, wherein the photo-addressable thermally developable element further includes a hydrazine compound represented by the formula (I): ##STR1## wherein: Z represents the necessary atoms to close a heterocyclic ring which is either a five-membered ring containing at least two heteroatoms or a six-membered ring, which ring may carry one or more fused-on rings, and which ring must contain a C--H bond permitting oxidative aromatisation to an acyl-onium group by means of a hydride shift or a consecutive 2-electron-proton transfer; each of R.sup.1 and R.sup.2 independently represents a hydrogen atom or an alkali-labile group giving rise to a hydrogen atom on hydrolysis; X is an acyl group selected from the group consisting of CO--R.sup.3, CS--R.sup.4, PO--R.sup.5 R.sup.6 and (CN--R.sup.7)--R.sup.8, wherein each of R.sup.3 to R.sup.8 independently represents alkyl, aryl, cycloalkyl, heterocycloalkyl, heteroaryl, O-alkyl, O-aryl, O-heteroaryl, O-heterocycloalkyl, S-alkyl, S-aryl, S-heterocycloalkyl, S-heteroaryl or N--R.sup.9 R.sup.10, wherein each of R.sup.9 and R.sup.10 independently represents hydrogen, aryl, alkyl, heteroaryl, heterocycloalkyl or acyl as defined for X, and wherein R.sup.5 together with R.sup.6, and R.sup.9 together with R.sup.10 may represent the necessary atoms to close a ring.
摘要翻译： 一种光热记录材料，其包括载体和可光寻址的热显影元件，其含有基本上不光敏的有机银盐，与其热处理关系的还原剂，与染料光谱感光并与基本上 光敏性有机银盐和粘合剂，其中光寻址热可显影元件还包括由式（I）表示的肼化合物：其中：Z表示关闭杂环的必要原子，其为五元 含有至少两个杂原子或六元环的环，该环可以携带一个或多个稠合环，并且哪个环必须含有CH键，其允许通过氢化物位移或酰基取代基对酰基进行氧化芳构化 连续的2电子 - 质子转移; R1和R2各自独立地表示在水解时产生氢原子的氢原子或碱不稳定基团; X是选自CO-R3，CS-R4，PO-R5R6和（CN-R7）-R8的酰基，其中R3至R8各自独立地表示烷基，芳基，环烷基，杂环烷基，杂芳基，O - 烷基，O-芳基，O-杂芳基，O-杂环烷基，S-烷基，S-芳基，S-杂环烷基，S-杂芳基或N-R9R10，其中R 9和R 10各自独立地表示氢，芳基，烷基，杂芳基 ，如对X所定义的杂环烷基或酰基，并且其中R 5和R 6与R 10一起可以表示关闭环的必要原子。
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公开(公告)号：US5883042A
公开(公告)日：1999-03-16
申请号：US862813
申请日：1997-05-30
申请人： Geert Defieuw , Wim Mues , Dirk Quintens , Ivan Hoogmartens
发明人： Geert Defieuw , Wim Mues , Dirk Quintens , Ivan Hoogmartens
CPC分类号： G03C1/49872 , G03C1/4989 , G03C1/7614
摘要： A (photo)thermographic recording material comprising a (photo-addressable) thermosensitive element on one side of a water resistant support and an outermost backside layer on the other side of the water resistant support, the (photo-addressable) thermosensitive element comprising a substantially light-insensitive organic silver salt, an organic reducing agent for the substantially light-insensitive organic silver salt in thermal working relationship therewith(, photosensitive silver halide in catalytic association with the substantially light insensitive organic silver salt) and a binder and the outermost backside layer comprising polymeric beads, characterized in that an outermost layer on the side of the water resistant support with the (photo-addressable) thermosensitive element does not contain a fluorine-containing polymeric surfactant and the static frictional coefficient between the outermost layer on the side of the water resistant support with the (photo-addressable) thermosensitive element and the outermost backside layer is .ltoreq.0.24 and/or the outermost backside layer of the (photo)thermographic recording material has an R.sub.z determined according to DIN 4768/1 of >1.75 .mu.m; and a (photo)thermographic recording process therefor.
摘要翻译： 一种（光）热成像记录材料，其在防水支架的一侧上包括（光寻址）热敏元件，在防水支架的另一侧上包括最外侧背面层，所述（可光寻址）热敏元件包括基本上 光不敏感有机银盐，与其热工作关系中的基本上不光泽的有机银盐的有机还原剂（与感光卤化银与基本上不敏感的有机银盐催化缔合）和粘合剂以及最外侧背面层 其特征在于，具有（可光寻址）热敏元件的防水支架一侧的最外层不含有含氟聚合物表面活性剂，并且在该侧面上的最外层之间的静态摩擦系数 防水支架（可光寻址）热固 （Photo）热敏照相记录材料的最外侧背面层具有根据DIN 4768/1测定的大于1.75μm的Rz; 和（照片）热成像记录方法。
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19.发明申请Binders for use in the thermosensitive elements of substantially light-insensitive thermographic recording materials 审中-公开用于基本上不透光的热敏记录材料的热敏元件的粘合剂公开(公告)号：US20050003315A1
公开(公告)日：2005-01-06
申请号：US10859528
申请日：2004-06-02
CPC分类号： G03C1/4989 , B41M5/3372 , B41M5/44 , B41M5/443 , B41M2205/40 , G03C1/04
摘要： A substantially light-insensitive monosheet thermographic recording material comprising a support and on one side of the support a thermosensitive element, the thermosensitive element comprising at least one substantially light-insensitive silver salt of a carboxylic acid, at least one reducing agent therefor in thermal working relationship therewith and at least one binder, the at least one binder comprising at least one first polymer consisting of vinyl aceto-acetal monomer units, vinyl butyral monomer units and monomer units selected from the group consisting of, vinyl alcohol, vinyl acetate and itaconic acid monomer units, wherein the weight ratio of the at least one binder to the light-insensitive silver salt(s) of a carboxylic acid in the thermosensitive element is greater than 1.5; and the at least one binder optionally contains less than 40% by weight of a second polymer consisting of vinyl butyral monomer units and optionally vinyl alcohol and/or vinyl acetate monomer units.
摘要翻译： 一种基本上不光敏的单片热成像记录材料，其包含支撑体，并且在支撑体的一侧上具有热敏元件，所述热敏元件包含至少一种基本上不受光敏的羧酸银盐，至少一种用于热加工的还原剂 与至少一种粘合剂，所述至少一种粘合剂包含至少一种由乙烯基乙酰 - 缩醛单体单元，乙烯基缩丁醛单体单元和选自由乙烯醇，乙酸乙烯酯和衣康酸组成的组的单体单元组成的第一聚合物 单体单元，其中所述热敏元件中所述至少一种粘合剂与所述不敏感的羧酸的银盐的重量比大于1.5; 并且所述至少一种粘合剂任选地包含小于40重量％的由乙烯醇缩丁醛单体单元和任选的乙烯醇和/或乙酸乙烯酯单体单元组成的第二聚合物。
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20.发明申请公开(公告)号：US20050003298A1
公开(公告)日：2005-01-06
申请号：US10859288
申请日：2004-06-02
CPC分类号： G03C1/4989 , G03C1/04 , G03C1/49863
摘要： A substantially light-insensitive monosheet thermographic recording material comprising a support and on one side of the support a thermosensitive element, the thermosensitive element comprising at least one substantially light-insensitive silver salt of a carboxylic acid, at least one reducing agent therefor in thermal working relationship therewith and at least one binder, the at least one binder comprising at least one first polymer consisting of vinyl aceto-acetal monomer units and optionally monomer units selected from the group consisting of vinyl alcohol, vinyl acetate and itaconic acid monomer units, wherein the weight ratio of the at least one binder to the light-insensitive silver salt(s) of a carboxylic acid in the thermosensitive element is greater than 1.6; and the at least one binder optionally contains less than 40% by weight of a second polymer consisting of vinyl butyral monomer units and optionally vinyl alcohol and/or vinyl acetate monomer units.
摘要翻译： 一种基本上不光敏的单片热成像记录材料，其包含支撑体，并且在支撑体的一侧上具有热敏元件，所述热敏元件包含至少一种基本上不受光敏的羧酸银盐，至少一种用于热加工的还原剂 与至少一种粘合剂，所述至少一种粘合剂包含至少一种由乙烯基乙酰 - 缩醛单体单元组成的第一聚合物和任选的选自乙烯醇，乙酸乙烯酯和衣康酸单体单元的单体单元，其中 所述至少一种粘合剂与所述热敏元件中羧酸的不敏感的银盐的重量比大于1.6; 并且所述至少一种粘合剂任选地包含小于40重量％的由乙烯醇缩丁醛单体单元和任选的乙烯醇和/或乙酸乙烯酯单体单元组成的第二聚合物。
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