公开(公告)号：US4728417A

公开(公告)日：1988-03-01

申请号：US887689

申请日：1986-07-21

Applicant: Arthur W. Aldag, Jr. ,  Simon G. Kukes ,  Stephen L. Parrott

Inventor： Arthur W. Aldag, Jr. ,  Simon G. Kukes ,  Stephen L. Parrott

IPC: C10G45/04 ,  B01J31/00 ,  C10G45/06 ,  C10G45/10 ,  C10G45/12 ,  C10G45/16 ,  C10G45/60

CPC classification number: C10G45/16

Abstract: An additive comprising a mixture of at least one decomposable molybdenum compound selected from the group consisting of molybdenum dithiophosphates and molybdenum dithiocarbamates and at least one decomposable nickel compound selected from the group consisting of nickel dithiophosphates and nickel dithiocarbamates is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing the additive is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the inventive additive may be commenced when the catalyst is new, partially deativated or spent with a beneficial result occuring in each case.

Abstract translation: 包含选自二硫代磷酸钼和二硫代氨基甲酸钼的至少一种可分解​​的钼化合物和至少一种选自二硫代磷酸镍和二硫代氨基甲酸镍的可分解的镍化合物的混合物的添加剂与含烃进料流 。 然后将含有添加剂的含烃进料物流在加氢精制过程中与包含选自氧化铝，二氧化硅和二氧化硅 - 氧化铝的载体的催化剂组合物和包含至少一种选自组VIB的金属的组合物 VIIB和第八期。 本发明添加剂的引入可以在催化剂是新的，部分脱盐的或在每种情况下产生有益结果的情况下消耗的时候开始。

公开(公告)号：US4724227A

公开(公告)日：1988-02-09

申请号：US52529

申请日：1987-05-19

Applicant: Simon G. Kukes ,  Stephen L. Parrott

Inventor： Simon G. Kukes ,  Stephen L. Parrott

IPC: B01J23/755 ,  B01J27/185 ,  C10G45/06 ,  B01J21/04 ,  B01J21/06 ,  B01J23/74

CPC classification number: C10G45/06 ,  B01J23/755 ,  B01J27/1853

Abstract: A composition of matter comprising alumina, at least one compound of nickel, at least one compound of zirconium and at least one compound containing phosphorus and oxygen is prepared by a process comprising the steps of impregnating an alumina-containing support material with an aqueous solution containing at least one nickel compound and at least one zirconium compound, drying, impregnating the Ni/Zr-impregnated material with an aqueous solution containing at least one P-O compound, drying and calcining. The composition of matter of this invention is useful as a catalyst for hydrotreating substantially liquid hydrocarbon-containing feed streams (particularly heavy oils) which also contain compounds of nickel, vanadium and sulfur.

Abstract translation: 包含氧化铝，至少一种镍化合物，至少一种锆化合物和至少一种含磷和氧化合物的化合物的组合物通过包括以下步骤的方法制备，所述方法包括：将含氧化铝的载体材料用含有 至少一种镍化合物和至少一种锆化合物，用含有至少一种PO化合物的水溶液干燥浸渍Ni / Zr浸渍的材料，进行干燥和煅烧。 本发明的物质组合物可用作加氢处理基本上液体含烃的进料流（特别是重油）的催化剂，其还含有镍，钒和硫化合物。

公开(公告)号：US4707465A

公开(公告)日：1987-11-17

申请号：US645385

申请日：1984-08-29

Applicant: Simon G. Kukes

Inventor： Simon G. Kukes

IPC: B01J27/02 ,  C07C6/04 ,  B01J27/047 ,  B01J27/051

CPC classification number: C07C6/04 ,  B01J27/02

Abstract: An improved olefin disproportionation catalyst produced by contacting (a) molybdenum or tungsten oxide supported on inorganic refractory oxide, and (B) a metal dithionite.

Abstract translation: 通过使（a）负载在无机难熔氧化物上的钼或氧化钨和（B）金属连二硫酸盐接触而制备的改进的烯烃歧化催化剂。

公开(公告)号：US4705768A

公开(公告)日：1987-11-10

申请号：US4514

申请日：1987-01-20

Applicant: Daniel M. Coombs ,  Ted H. Cymbaluk ,  Brent J. Bertus ,  Simon G. Kukes

Inventor： Daniel M. Coombs ,  Ted H. Cymbaluk ,  Brent J. Bertus ,  Simon G. Kukes

IPC: B01J23/755 ,  B01J27/185 ,  C10G45/06 ,  B01J27/198 ,  B01J27/18 ,  B01J27/19

CPC classification number: C10G45/06 ,  B01J23/755 ,  B01J27/1853

Abstract: A new composition of matter comprises nickel phosphate and titanium phosphate, prepared by coprecipitation. A process for removing metals from a hydrocarbon-containing feed stream, in particular a heavy oil, comprises hydrotreatment in the presence of a solid catalyst composition comprising coprecipitated nickel phosphate and titanium phosphate.

Abstract translation: 一种新的物质组成包括由共沉淀制备的磷酸镍和磷酸钛。 从含烃进料流，特别是重油中除去金属的方法包括在包含共沉淀的磷酸镍和磷酸钛的固体催化剂组合物的存在下进行加氢处理。

公开(公告)号：US4671866A

公开(公告)日：1987-06-09

申请号：US832937

申请日：1986-02-26

Applicant: Daniel M. Coombs ,  Gerhard P. Nowack ,  Brent J. Bertus ,  Simon G. Kukes

Inventor： Daniel M. Coombs ,  Gerhard P. Nowack ,  Brent J. Bertus ,  Simon G. Kukes

IPC: B01J27/18 ,  C10G45/04 ,  C10G45/00

CPC classification number: C10G45/04 ,  B01J27/1817

Abstract: A process for removing metals from a hydrocarbon-containing feed stream comprises hydrotreatment in the presence of a solid catalyst composition comprising aluminum phosphate, zirconium phosphate and copper phosphate (preferably coprecipitated).

Abstract translation: 从含烃进料流中除去金属的方法包括在包含磷酸铝，磷酸锆和磷酸铜（优选共沉淀）的固体催化剂组合物存在下的加氢处理。

公开(公告)号：US4636487A

公开(公告)日：1987-01-13

申请号：US776305

申请日：1985-09-16

Applicant: Stephen L. Parrott ,  Simon G. Kukes ,  Howard F. Efner

Inventor： Stephen L. Parrott ,  Simon G. Kukes ,  Howard F. Efner

IPC: B01J37/20 ,  C10G45/04 ,  B01J31/00 ,  B01J21/02 ,  B01J27/188 ,  B01J27/19

CPC classification number: B01J37/20 ,  C10G45/04

Abstract: A highly active promoted catalyst, for use in hydrotreating oils, comprising a support, selected from the group consisting of alumina, silica and silica-alumina, and a promoter comprising a hydroxymercaptide of one or more metals, wherein said metals are selected from Group IB, Group VIB, Group VIIB or Group VIII of the Periodic Table, is economically produced without the use of a high temperature calcination or high temperature presulfiding step. In accordance with the invention, the hydroxymercaptide promoter used in said promoted catalyst may be the reaction product of a mercaptoalcohol and one or more metal compounds, wherein said metal compounds comprise metals selected from Group IB, Group VIB, Group VIIB or Group VIII of the Periodic Table.

Abstract translation: 一种用于加氢处理油的高活性促进催化剂，其包括选自氧化铝，二氧化硅和二氧化硅 - 氧化铝的载体，以及包含一种或多种金属的羟基巯基的助催化剂，其中所述金属选自IB组 ，VIB族，VIIB族或VIII族，经济地制备而不使用高温煅烧或高温预硫化步骤。 根据本发明，用于所述促进的催化剂中的羟基巯基促进剂可以是巯基醇和一种或多种金属化合物的反应产物，其中所述金属化合物包括选自IB组，VIB族，VIIB族或VIII族的金属 周期表。

公开(公告)号：US4613719A

公开(公告)日：1986-09-23

申请号：US788297

申请日：1985-10-17

Applicant: Simon G. Kukes ,  Gerhard P. Nowack ,  Robert L. Banks

Inventor： Simon G. Kukes ,  Gerhard P. Nowack ,  Robert L. Banks

IPC: B01J27/18 ,  C07C2/18 ,  C07C2/02

CPC classification number: C07C2/18 ,  B01J27/1817 ,  C07C2527/167

Abstract: A process for oligomerizing olefins to C.sub.5 -C.sub.12 hydrocarbons comprises contacting, under suitable reaction conditions, at least one olefin having from 2 to 4 carbon atoms per molecule, free hydrogen and a catalyst composition comprising chemically bound copper, phosphorus and oxygen. Preferably, the olefin is propylene or 1-butene. The preferred catalyst composition comprises a mixture of copper(II) orthophosphate, zirconium orthophosphate and aluminum orthophosphate, preferably formed by coprecipitation.

Abstract translation: 将烯烃低聚为C 5 -C 12烃的方法包括在合适的反应条件下使每分子具有2至4个碳原子的至少一种烯烃，游离氢和包含化学键合的铜，磷和氧的催化剂组合物接触。 优选地，烯烃是丙烯或1-丁烯。 优选的催化剂组合物包括正磷酸铜（II），正磷酸锆和正磷酸铝的混合物，优选通过共沉淀形成。

公开(公告)号：US4582594A

公开(公告)日：1986-04-15

申请号：US647220

申请日：1984-09-04

Applicant: Simon G. Kukes ,  Robert J. Hogan ,  Daniel M. Coombs ,  Howard F. Efner

Inventor： Simon G. Kukes ,  Robert J. Hogan ,  Daniel M. Coombs ,  Howard F. Efner

IPC: C10G45/04 ,  C10G45/16 ,  C10G47/12 ,  C10G47/14

CPC classification number: C10G45/16 ,  C10G45/04

Abstract: The reaction product of a mercaptoalcohol and a molybdenum compound selected from the group consisting of molybdic acids, alkali metal salts of molybdic acids and ammonium salts of molybdic acids is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such reaction product is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of Al.sub.2 O.sub.3, SiO.sub.2, Al.sub.2 O.sub.3 --SiO.sub.2, Al.sub.2 O.sub.3 --TiO.sub.2, Al.sub.2 O.sub.3 --P.sub.2 O.sub.5, Al.sub.2 O.sub.3 --BPO.sub.4, Al.sub.2 O.sub.3 --AlPO.sub.4, Al.sub.2 O.sub.3 --Zr.sub.3 (PO.sub.4).sub.4, Al.sub.2 O.sub.3 --SnO.sub.2 and Al.sub.2 O.sub.3 --ZnO and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the reaction product may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occuring in each case.

Abstract translation: 巯基醇和选自钼酸，钼酸的碱金属盐和钼酸铵盐的钼化合物的反应产物与含烃进料流混合。 含有该反应产物的含烃进料流然后在加氢精制过程中与包含选自Al2O3，SiO2，Al2O3-SiO2，Al2O3-TiO2，Al2O3-P2O5，Al2O3-BPO4， Al2O3-AlPO4，Al2O3-Zr3（PO4）4，Al2O3-SnO2和Al2O3-ZnO，以及包含选自元素周期表第VIB族，第VIIB族和第VIII族中的至少一种金属的促进剂。 反应产物的引入可以在催化剂是新的，部分失活的或在每一种情况下产生有益结果的情况下消耗或开始。

公开(公告)号：US4578179A

公开(公告)日：1986-03-25

申请号：US553445

申请日：1983-11-18

Applicant: Simon G. Kukes ,  Marvin M. Johnson ,  Daniel J. Strope ,  Robert J. Hogan

Inventor： Simon G. Kukes ,  Marvin M. Johnson ,  Daniel J. Strope ,  Robert J. Hogan

IPC: B01J23/00 ,  C10G45/04 ,  C10G45/16 ,  C10G45/08 ,  C10G47/06 ,  C10G47/12

CPC classification number: C10G45/16 ,  C10G45/04

Abstract: A treated decomposable compound of molybdenum, which has been prepared by the catalytic hydrogenation of a decomposable compound of molybdenum, wherein the molybdenum has a valence state greater than zero, or by the treating of the decomposable compound of molybdenum with a reducing agent, is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such treated decomposable compound of molybdenum is then contacted with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica alumina and a promoter comprising at least one metal selected from the group consisting of Group VIB, Group VIIB, and Group VIII of the Periodic Table to reduce the concentration of metals, sulfur, nitrogen, Ramsbottom carbon residue and/or heavies contained in the hydrocarbon-containing feed stream.

Abstract translation: 通过钼的可分解化合物的催化氢化制备的钼的经处理的可分解化合物，其中钼具有大于零的价态，或通过用还原剂处理钼的可分解化合物，被混合 与含烃的进料流。 然后将含有这种经处理的可分解钼的化合物的含烃进料流与包含选自氧化铝，二氧化硅和二氧化硅氧化铝的载体的催化剂组合物和包含至少一种选自组 VIB，VIIB族和VIII族，以减少含烃进料流中所含的金属，硫，氮，Ramsbottom碳残余物和/或重质物的浓度。

公开(公告)号：US4560468A

公开(公告)日：1985-12-24

申请号：US596982

申请日：1984-04-05

Applicant: Simon G. Kukes ,  Robert J. Hogan ,  Daniel M. Coombs ,  Thomas Davis ,  Howard F. Efner

Inventor： Simon G. Kukes ,  Robert J. Hogan ,  Daniel M. Coombs ,  Thomas Davis ,  Howard F. Efner

IPC: B01J23/00 ,  B01J31/26 ,  C10G45/04 ,  C10G45/16 ,  C10G45/12 ,  C10G47/12 ,  C10G47/16

CPC classification number: C10G45/04 ,  C10G45/16

Abstract: At least one decomposable molybdenum dithiophosphate compound is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable molybdenum dithiophosphate compound is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the decomposable molybdenum dithiophosphate compound may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occuring in each case.

Abstract translation: 将至少一种可分解​​的二硫代磷酸钼化合物与含烃进料流混合。 然后将含有这种可分解的二硫代磷酸钼化合物的含烃进料流在加氢精制过程中与包含选自氧化铝，二氧化硅和二氧化硅 - 氧化铝的载体的催化剂组合物和包含至少一种选自组 VIB，VIIB和VIII组。 当可催化的新二硫代磷酸酯化合物引入时，可以在每种情况下产生有益效果的部分失活或消耗。