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    Process for in-situ production of low dissolved hydrogen sulfide, degassed, sulfur from claus sulfur recovery
    1.
    发明授权
    Process for in-situ production of low dissolved hydrogen sulfide, degassed, sulfur from claus sulfur recovery 有权
    原位生产低溶解硫化氢，脱气，硫从硫酸回收的工艺

    公开(公告)号：US09192887B2

    公开(公告)日：2015-11-24

    申请号：US14303946

    申请日：2014-06-13

    申请人： PHILLIPS 66 COMPANY

    发明人： Alfred E. Keller

    IPC分类号： B01D5/00 ,  C01B17/04 ,  C01B17/05 ,  F25J1/00 ,  B01D53/00 ,  C01B17/02

    CPC分类号： B01D53/002 ,  B01D5/00 ,  B01D5/0009 ,  B01D5/0012 ,  B01D5/0051 ,  B01D5/0069 ,  B01D5/0093 ,  B01J8/02 ,  C01B17/0232 ,  C01B17/0439 ,  C01B17/0447 ,  C01B17/0456 ,  C01B17/0469 ,  C01B17/05 ,  F25J1/00 ,  F25J1/0002

    摘要： A process of producing degassed liquid sulfur within a vertical sulfur condenser may include providing a plurality of condenser tubes within an external casing; submerging exit ends of the plurality of condenser tubes within a liquid reservoir resulting in submerged exit ends of the plurality of condenser tubes; passing the Claus process gas into an inlet end of the plurality of condenser tubes; condensing the Claus process gas within the condenser tubes to produce condensed Claus process gas within the plurality of condenser tubes; and collecting the condensed Claus process gas in the liquid reservoir upon exiting of the condensed Claus process gas at an exit end of the plurality of condenser tubes. The process may further include converting hydrogen sulfide by the Claus reaction 2H2S+SO23/xSx+2H2O, and decomposing polysulfanes to hydrogen sulfide and sulfur, wherein elemental sulfur is freed from hydrogen sulfide.

    摘要翻译： 在垂直硫冷凝器内产生脱气液硫的过程可包括在外壳内提供多个冷凝器管; 将多个冷凝器管的出口端浸没在液体储存器内，导致多个冷凝器管的浸没出口端; 将Claus工艺气体送入多个冷凝器管的入口端; 在所述冷凝器管内冷凝所述Claus工艺气体以在所述多个冷凝器管内产生冷凝的Claus工艺气体; 以及在所述多个冷凝器管的出口端离开所述冷凝的Claus工艺气体之后，在所述液体储存器中收集所述冷凝的Claus工艺气体。 该方法可以进一步包括通过克劳斯反应2H 2 S + SO 2 3 / xS x + 2H 2 O转化硫化氢，并将多硫烷分解成硫化氢和硫，其中元素硫不含硫化氢。

    Process for the selective oxidation of hydrogen sulphide
    2.
    发明授权
    Process for the selective oxidation of hydrogen sulphide 失效
    硫化氢选择性氧化的方法

    公开(公告)号：US08524189B2

    公开(公告)日：2013-09-03

    申请号：US13131130

    申请日：2009-11-26

    申请人： Arnab Chatterjee ,  Carolus Matthias Anna Maria Mesters ,  Ronald Jan Schoonebeek

    发明人： Arnab Chatterjee ,  Carolus Matthias Anna Maria Mesters ,  Ronald Jan Schoonebeek

    IPC分类号： C01B17/04 ,  C10L3/10

    CPC分类号： B01D53/8612 ,  B01D2251/10 ,  B01D2255/20707 ,  B01D2256/16 ,  B01D2256/24 ,  B01D2257/304 ,  C01B17/0469

    摘要： The present invention provides a process for the selective oxidation of hydrogen sulphide contained in a hydrogen sulphide-containing hydrocarbon feed gas to elemental sulphur. The hydrogen sulphide-containing hydrocarbon feed gas and a sulphur dioxide-containing gas are supplied to a reaction zone containing a TiO2-comprising catalyst, wherein elemental sulphur and a gaseous stream depleted in hydrogen sulphide are formed. The gas feeds are contacted with the TiO2 containing catalyst at elevated pressure and at a temperature in the range of from 120 and below 160 ° C., under such conditions that the elemental sulphur formed is essentially in liquid form. At least part of the sulphur dioxide-containing gas is obtained by combusting elemental sulphur to obtain a gaseous mixture of sulphur dioxide and nitrogen and then concentrating the gaseous mixture to provide the sulphur dioxide-containing gas.

    摘要翻译： 本发明提供了将含硫化氢的烃进料气体中所含的硫化氢选择性氧化成元素硫的方法。 将含硫化氢的烃进料气体和含二氧化硫的气体供应到含有TiO 2的催化剂的反应区，其中形成元素硫和贫硫化氢气体。 气体进料在升高的压力下和在120℃和低于160℃的温度下，在形成的元素硫基本上是液体形式的条件下与含TiO 2的催化剂接触。 通过燃烧元素硫以获得二氧化硫和氮的气体混合物，然后浓缩气体混合物以提供含二氧化硫的气体，获得至少部分含二氧化硫的气体。

    Process for producing a gas stream depleted of hydrogen sulphide
    3.
    发明授权
    Process for producing a gas stream depleted of hydrogen sulphide 失效
    生产耗尽硫化氢的气流的方法

    公开(公告)号：US07727507B2

    公开(公告)日：2010-06-01

    申请号：US11887292

    申请日：2006-03-28

    申请人： Carolus Matthias Anna Maria Mesters ,  Isaac Cornelis Van Den Born

    发明人： Carolus Matthias Anna Maria Mesters ,  Isaac Cornelis Van Den Born

    IPC分类号： C01B17/04 ,  C01B17/50

    CPC分类号： C01B17/54 ,  B01D53/8612 ,  C01B17/0469 ,  C01B17/05

    摘要： A process for treating a gas stream comprising H2S that includes the step of selectively oxidizing the H2S of the gas stream within a catalytic zone containing an oxidation catalyst and in the presence of an inert liquid medium and molecular oxygen to form elemental sulfur and a gas stream depleted of H2S. A liquid stream yielded from the catalytic zone and containing the inert liquid medium and liquid elemental sulfur undergoes a separation into a first liquid phase rich in the inert liquid medium and a second liquid phase rich in elemental sulfur. Either at least a part of the liquid stream or at least a part of the second liquid phase, or both, undergoes a combustion to form a fluid stream that comprises sulfur dioxide.

    摘要翻译： 一种用于处理包含H 2 S的气流的方法，其包括在含有氧化催化剂的催化区内和在惰性液体介质和分子氧的存在下选择性地氧化气流的H 2 S的步骤，以形成元素硫和气流 耗尽H2S。 从催化区产生的含有惰性液体介质的液体流，液体元素硫经历分离成富含惰性液体介质的第一液相和富含元素硫的第二液相。 液态物流或至少一部分第二液相或两者的至少一部分经历燃烧以形成包含二氧化硫的流体物流。

    Sulfur gas treatment process
    4.
    发明授权
    Sulfur gas treatment process 有权
    硫气处理工艺

    公开(公告)号：US07250149B1

    公开(公告)日：2007-07-31

    申请号：US10785907

    申请日：2004-02-24

    申请人： Strom W. Smith

    发明人： Strom W. Smith

    IPC分类号： B01D53/58 ,  C01B17/04 ,  G05D7/00

    CPC分类号： B01D53/8612 ,  B01D53/58 ,  B01D2257/304 ,  B01D2257/406 ,  C01B17/0421 ,  C01B17/0469 ,  Y02P20/129 ,  Y10S423/05

    摘要： The present invention comprises a method of treating an off-gas stream from a refining process to remove sulfur compounds. A portion of the off-gas stream containing hydrogen sulfide is injected at the front end of the thermal reactor and in at least one other location downstream of the thermal reactor. A ratio of hydrogen sulfide to sulfur dioxide at the outlet of the thermal reactor is less than the stoichiometric requirement. The ratio is adjusted downstream of the thermal reactor so that a ratio of hydrogen sulfide to sulfur dioxide is maintained substantially in excess of the stoichiometric requirement for a Claus reaction. The tail gas, containing hydrogen sulfide but virtually no sulfur dioxide, is treated by a process including removal of water and introducing sulfur dioxide into the tail gas in a stoichiometricly balanced quantity and processing the tail gas in a Claus reactor.

    摘要翻译： 本发明包括一种处理来自精制方法的废气流以除去硫化合物的方法。 含有硫化氢的废气流的一部分在热反应器的前端和热反应器的下游的至少另一个位置注入。 热反应器出口处的硫化氢与二氧化硫的比例小于化学计量要求。 该比例在热反应器的下游调节，使得硫化氢与二氧化硫的比例基本上保持在克劳斯反应的化学计量要求之上。 包含硫化氢但实质上不含二氧化硫的尾气通过包括去除水并以化学计量平衡的量将二氧化硫引入尾气中并在克劳斯反应器中处理尾气的方法来处理。

    Process for the high pressure degassing of hydrogen sulfide from liquid sulfur
    5.
    发明授权
    Process for the high pressure degassing of hydrogen sulfide from liquid sulfur 失效
    硫化氢从液态硫高压脱气的工艺

    公开(公告)号：US5632967A

    公开(公告)日：1997-05-27

    申请号：US531186

    申请日：1995-09-19

    申请人： Elmo Nasato

    发明人： Elmo Nasato

    IPC分类号： C01B17/02 ,  C01B17/04

    CPC分类号： C01B17/0232 ,  C01B17/0469

    摘要： Disclosed is a process for degassing liquid sulfur under pressure. A stream of liquid sulfur containing polysulfides and hydrogen sulfide and a stream of an oxidizing gas are introduced into a vessel and intimately mixed to provide intimate contact between the two streams. The streams are passed through the vessel at a pressure of at least about 40 psig and at a temperature and for a residence time sufficient to remove substantially all of the polysulfides and hydrogen sulfide from the liquid sulfur.

    摘要翻译： 公开了一种在压力下对液态硫进行脱气的方法。 将含硫多硫化物和硫化氢的液流和氧化气体流引入容器中并充分混合以提供两种物流之间的紧密接触。 流以至少约40psig的压力和在足以从液态硫中基本上除去所有多硫化物和硫化氢的温度和停留时间通过容器。

    Process for removing sulphur compounds contained in a residual gas
    6.
    发明授权
    Process for removing sulphur compounds contained in a residual gas 失效
    用于除去残留气体中所含的硫化合物的方法

    公开(公告)号：US4980146A

    公开(公告)日：1990-12-25

    申请号：US75749

    申请日：1987-06-25

    申请人： Georges Kvasnikoff ,  Jean Nougayrede ,  Andre Philippe

    发明人： Georges Kvasnikoff ,  Jean Nougayrede ,  Andre Philippe

    IPC分类号： B01D53/86 ,  C01B17/04

    CPC分类号： C01B17/0469 ,  B01D53/8615 ,  C01B17/0456 ,  C01B17/046 ,  C01B17/0465 ,  Y02P20/584

    摘要： Process for removing sulfur compounds contained in a residual gas with recovery of said compounds in the form of sulfur, wherein a gas obtained from a residual gas containing H.sub.2 S and SO.sub.2 and having a temperature lower than 160.degree. C. is subjected to a catalytic CLAUS reaction phase with deposition of sulfur on the catalyst and periodic regeneration of the sulfur-laden catalyst and cooling of the regenerated catalyst. The gas brought in contact with the CLAUS catalyst is produced by subjecting the residual gas to a hydrogenation and hydrolysis treatment to provide the sulfur compounds in the unique form of H.sub.2 S and to cooling with water separation by condensation and then to catalytic oxidation of H.sub.2 S in CLAUS stoichiometry with cooling of the gas stream obtained from the oxidation step under 160.degree. C. in order to separate the sulfur by condensation. Application to the purification of the residual gases emitted by CLAUS sulfur plants.

    摘要翻译： PCT No.PCT / FR86 / 00365 Sec。 371日期1987年6月25日第 102（e）日期1987年6月25日PCT提交1986年10月24日PCT公布。 公开号WO87 / 02653 日期：1987年5月7日。通过回收硫形式的所述化合物来除去残留气体中所含的硫化合物的方法，其中从含有H 2 S和SO 2的残余气体获得的温度低于160℃的气体为 经过催化CLAUS反应相，同时在催化剂上沉积硫并周期性地再生含硫催化剂并冷却再生催化剂。 与CLAUS催化剂接触的气体是通过使残余气体进行氢化和水解处理以提供独特形式的硫化氢的硫化合物，并通过冷凝进行水分离冷却，然后在CLAUS中催化氧化H 2 S， 通过在160℃下从氧化步骤获得的气流冷却来进行化学计量，以便通过冷凝分离硫。 应用于CLAUS硫磺植物排放的残留气体的净化。