公开(公告)号：US20110015349A1

公开(公告)日：2011-01-20

申请号：US12658115

申请日：2010-02-02

Applicant: Rudolf Faust ,  Jae Cheol Cho

Inventor： Rudolf Faust ,  Jae Cheol Cho

IPC: C08F220/06 ,  C08F8/02 ,  C08F8/42

CPC classification number: C08F297/026 ,  C08F8/00 ,  C08F110/10 ,  C08F295/00 ,  C08F297/00 ,  C08F297/02 ,  C08F10/10 ,  C08F4/00 ,  C08F2/38 ,  C08F2500/03 ,  C08F2500/01

Abstract: According to an aspect of the present invention, a method is provided in which a double diphenylethylene compound is reacted with a polymer that contains a carbocationically terminated chain thereby providing a 1,1-diphenylene end-functionalized chain. Subsequently, an alkylating agent is reacted with the 1,1-diphenylene end-functionalized chain, thereby providing an alkylated 1,1-diphenylene end-functionalized chain. In some embodiments, the method further comprises (a) optionally combining a 1,1-diphenylorganolithium compound with the alkylated 1,1-diphenylene end-functionalized polymer followed by (b) reacting an organolithium compound with the alkylated 1,1-diphenylene end-functionalized polymer. This provides an anionically terminated polymer, which can be used, for example, in subsequent anionic polymerization and coupling reactions. According to another aspect of the present invention, a novel polymer is provided that comprises a polymer chain, which chain further comprises the following: (a) a plurality of constitutional units that correspond to cationically polymerizable monomer species and (b) an end-cap comprising a group or a group, where R is a branched or unbranched alkyl group containing from 1 to 20 carbons and R1 is a branched, unbranched, or cyclic alkyl group or an aryl group, containing from 1 to 20 carbons. Other aspects of the present invention relate to novel copolymers that comprise: (a) a first polymer block that comprises a plurality of constitutional units that correspond to isobutylene; and (b) a second polymer block that comprises a plurality of constitutional units that correspond to hydroxyethyl methacrylate.

Abstract translation: 根据本发明的一个方面，提供了一种方法，其中双二苯基乙烯化合物与含有碳阳离子末端链的聚合物反应，从而提供1,1-二亚苯基端官能化链。 随后，使烷基化剂与1,1-二亚苯基末端官能化链反应，从而提供烷基化的1,1-二亚苯基端官能化链。 在一些实施方案中，该方法还包括（a）任选地将1,1-二苯基有机锂化合物与烷基化的1,1-二亚苯基端官能化聚合物组合，然后（b）使有机锂化合物与烷基化的1,1-二亚苯基末端 官能化聚合物。 这提供了阴离子封端的聚合物，其可以用于例如随后的阴离子聚合和偶联反应。 根据本发明的另一方面，提供了一种包含聚合物链的新型聚合物，该链还包含以下物质：（a）多个与阳离子可聚合单体物质相对应的结构单元和（b）端帽 包括基团或基团，其中R是含有1至20个碳的支链或非支链烷基，R 1是含有1至20个碳的支链，非支链或环状烷基或芳基。 本发明的其它方面涉及包含以下的新型共聚物：（a）包含对应于异丁烯的多个结构单元的第一聚合物嵌段; 和（b）包含对应于甲基丙烯酸羟乙酯的多个结构单元的第二聚合物嵌段。

公开(公告)号：US07671158B2

公开(公告)日：2010-03-02

申请号：US11447403

申请日：2006-06-05

Applicant: Rudolf Faust ,  Jae Cheol Cho

Inventor： Rudolf Faust ,  Jae Cheol Cho

IPC: C08F10/10 ,  C08F110/10 ,  C08F210/10

CPC classification number: C08F297/026 ,  C08F8/00 ,  C08F110/10 ,  C08F295/00 ,  C08F297/00 ,  C08F297/02 ,  C08F10/10 ,  C08F4/00 ,  C08F2/38 ,  C08F2500/03 ,  C08F2500/01

Abstract: According to an aspect of the present invention, a method is provided in which a double diphenylethylene compound is reacted with a polymer that contains a carbocationically terminated chain thereby providing a 1,1-diphenylene end-functionalized chain. Subsequently, an alkylating agent is reacted with the 1,1-diphenylene end-functionalized chain, thereby providing an alkylated 1,1-diphenylene end-functionalized chain. In some embodiments, the method further comprises (a) optionally combining a 1,1-diphenylorganolithium compound with the alkylated 1,1-diphenylene end-functionalized polymer followed by (b) reacting an organolithium compound with the alkylated 1,1-diphenylene end-functionalized polymer. This provides an anionically terminated polymer, which can be used, for example, in subsequent anionic polymerization and coupling reactions. According to another aspect of the present invention, a novel polymer is provided that comprises a polymer chain, which chain further comprises the following: (a) a plurality of constitutional units that correspond to cationically polymerizable monomer species and (b) an end-cap comprising a group or a group, where R is a branched or unbranched alkyl group containing from 1 to 20 carbons and R1 is a branched, unbranched, or cyclic alkyl group or an aryl group, containing from 1 to 20 carbons. Other aspects of the present invention relate to novel copolymers that comprise: (a) a first polymer block that comprises a plurality of constitutional units that correspond to isobutylene; and (b) a second polymer block that comprises a plurality of constitutional units that correspond to hydroxyethyl methacrylate.

Abstract translation: 根据本发明的一个方面，提供了一种方法，其中双二苯基乙烯化合物与含有碳阳离子末端链的聚合物反应，从而提供1,1-二亚苯基端官能化链。 随后，使烷基化剂与1,1-二亚苯基末端官能化链反应，从而提供烷基化的1,1-二亚苯基端官能化链。 在一些实施方案中，该方法还包括（a）任选地将1,1-二苯基有机锂化合物与烷基化的1,1-二亚苯基端官能化聚合物组合，然后（b）使有机锂化合物与烷基化的1,1-二亚苯基末端 官能化聚合物。 这提供了阴离子封端的聚合物，其可以用于例如随后的阴离子聚合和偶联反应。 根据本发明的另一方面，提供了一种包含聚合物链的新型聚合物，该链还包含以下物质：（a）多个与阳离子可聚合单体物质相对应的结构单元和（b）端帽 包括基团或基团，其中R是含有1至20个碳的支链或非支链烷基，R 1是含有1至20个碳的支链，非支链或环状烷基或芳基。 本发明的其它方面涉及包含以下的新型共聚物：（a）包含对应于异丁烯的多个结构单元的第一聚合物嵌段; 和（b）包含对应于甲基丙烯酸羟乙酯的多个结构单元的第二聚合物嵌段。

公开(公告)号：US20080275202A1

公开(公告)日：2008-11-06

申请号：US11794964

申请日：2006-01-11

Applicant: Rudolf Faust ,  Jae Cheol Cho

Inventor： Rudolf Faust ,  Jae Cheol Cho

IPC: C08F4/10 ,  C08F226/06 ,  C08F4/12

CPC classification number: C08F8/00 ,  C08F8/02 ,  C08F210/10 ,  C08F290/042 ,  C08F293/005 ,  C08F295/00 ,  C08F297/02 ,  C08F297/00 ,  C08F10/10 ,  C08F226/06

Abstract: The present invention is directed to copolymers that include a plurality of constitutional units that correspond to cationically polymerizable monomer species and a second polymer block that comprises a plurality of constitutional units that correspond to an anionically polymerizable vinylpyridine, e.g., 2-vinylpyridine, and methods for making the same. Such copolymers can also include a linking moiety, e.g., a Formula (I) group, a Formula (II) group, or any combinations thereof.

Abstract translation: 本发明涉及包含对应于阳离子可聚合单体物质的多个结构单元和包含多个与阴离子可聚合乙烯基吡啶对应的结构单元的第二聚合物嵌段的共聚物，例如2-乙烯基吡啶，以及用于 做同样的事情 这种共聚物还可以包括连接部分，例如式（I）基团，式（II）基团或其任何组合。

公开(公告)号：US07056985B2

公开(公告)日：2006-06-06

申请号：US10776681

申请日：2004-02-11

Applicant: Rudolf Faust ,  Jae Cheol Cho

Inventor： Rudolf Faust ,  Jae Cheol Cho

IPC: C08F293/00

CPC classification number: C08F297/026 ,  C08F8/00 ,  C08F110/10 ,  C08F295/00 ,  C08F297/00 ,  C08F297/02 ,  C08F10/10 ,  C08F4/00 ,  C08F2/38 ,  C08F2500/03 ,  C08F2500/01

Abstract: According to an aspect of the present invention, a method is provided in which a double diphenylethylene compound is reacted with a polymer that contains a carbocationically terminated chain thereby providing a 1,1-diphenylene end-functionalized chain. Subsequently, an alkylating agent is reacted with the 1,1-diphenylene end-functionalized chain, thereby providing an alkylated 1,1-diphenylene end-functionalized chain. In some embodiments, the method further comprises (a) optionally combining a 1,1-diphenylorganolithium compound with the alkylated 1,1-diphenylene end-functionalized polymer followed by (b) reacting an organolithium compound with the alkylated 1,1-diphenylene end-functionalized polymer. This provides an anionically terminated polymer, which can be used, for example, in subsequent anionic polymerization and coupling reactions. According to another aspect of the present invention, a novel polymer is provided that comprises a polymer chain, which chain further comprises the following: (a) a plurality of constitutional units that correspond to cationically polymerizable monomer species and (b) an end-cap comprising a group or a group, where R is a branched or unbranched alkyl group containing from 1 to 20 carbons and R1 is a branched, unbranched, or cyclic alkyl group or an aryl group, containing from 1 to 20 carbons. Other aspects of the present invention relate to novel copolymers that comprise: (a) a first polymer block that comprises a plurality of constitutional units that correspond to isobutylene; and (b) a second polymer block that comprises a plurality of constitutional units that correspond to hydroxyethyl methacrylate.

Abstract translation: 根据本发明的一个方面，提供了一种方法，其中双二苯基乙烯化合物与含有碳阳离子末端链的聚合物反应，从而提供1,1-二亚苯基端官能化链。 随后，使烷基化剂与1,1-二亚苯基末端官能化链反应，从而提供烷基化的1,1-二亚苯基端官能化链。 在一些实施方案中，该方法还包括（a）任选地将1,1-二苯基有机锂化合物与烷基化的1,1-二亚苯基端官能化聚合物组合，然后（b）使有机锂化合物与烷基化的1,1-二亚苯基末端 官能化聚合物。 这提供了阴离子封端的聚合物，其可以用于例如随后的阴离子聚合和偶联反应。 根据本发明的另一方面，提供了一种包含聚合物链的新型聚合物，该链还包含以下物质：（a）多个与阳离子可聚合单体物质相对应的结构单元和（b）端帽 包括基团或基团，其中R是含有1至20个碳的支链或非支链烷基，R 1是支链，非支链或环状烷基或芳基，其含有1个 至20个碳。 本发明的其它方面涉及包含以下的新型共聚物：（a）包含对应于异丁烯的多个结构单元的第一聚合物嵌段; 和（b）包含对应于甲基丙烯酸羟乙酯的多个结构单元的第二聚合物嵌段。

公开(公告)号：US20080224099A1

公开(公告)日：2008-09-18

申请号：US12038138

申请日：2008-02-27

Applicant: Jinsang Kim ,  Jae Cheol Cho ,  Laura K. Povlich ,  David C. Martin

Inventor： Jinsang Kim ,  Jae Cheol Cho ,  Laura K. Povlich ,  David C. Martin

IPC: H01B1/00 ,  C07D495/04 ,  C07K14/48 ,  C07K14/475 ,  C07K14/00 ,  C07H3/00 ,  C07H21/00

CPC classification number: C07D495/04

Abstract: An electroconductive carboxylic acid functionalized monomer corresponding to Formula (I), wherein A represents a hydrogen or a carboxyl group. Polymerized monomers of Formula (I) conjugated with a biomolecule result in conjugated PEDOT polymers of Formula (III) wherein A is a hydrogen or a carboxylic acid group and B is a biomolecule selected from the group consisting of a peptide, a protein, a lipid, a carbohydrate and a polynucleotide. The biomolecule conjugated polymers can be disposed onto an electrically conductive substrate wherein the substrate has a first layer of PEDOT polymerized on a surface of the substrate and a second layer of biomolecule conjugated PEDOT polymer of Formula (III) polymerized on the first layer of PEDOT. The first and second layers form a charge transport material in electrical communication with the conductive substrate. The electrically conductive substrate further comprises a dopant.

Abstract translation: 对应于式（I）的导电羧酸官能化单体，其中A表示氢或羧基。 与生物分子缀合的式（I）的聚合单体导致式（III）的共轭PEDOT聚合物，其中A是氢或羧酸基团，B是选自肽，蛋白质，脂质的生物分子 ，碳水化合物和多核苷酸。 生物分子共轭聚合物可以设置在导电基底上，其中基底具有在基底表面上聚合的第一层PEDOT和在第一层PEDOT上聚合的式（III）的生物分子共轭PEDOT聚合物的第二层。 第一和第二层形成与导电基底电连通的电荷传输材料。 导电衬底还包括掺杂剂。

公开(公告)号：US07708908B2

公开(公告)日：2010-05-04

申请号：US12038138

申请日：2008-02-27

Applicant: Jinsang Kim ,  Jae Cheol Cho ,  Laura K. Povlich ,  David C. Martin

Inventor： Jinsang Kim ,  Jae Cheol Cho ,  Laura K. Povlich ,  David C. Martin

IPC: H01B1/12 ,  C08G75/00 ,  C07D333/10 ,  G01N31/00

CPC classification number: C07D495/04

Abstract: An electroconductive carboxylic acid functionalized monomer corresponding to Formula (I), wherein A represents a hydrogen or a carboxyl group. Polymerized monomers of Formula (I) conjugated with a biomolecule result in conjugated PEDOT polymers of Formula (III) wherein A is a hydrogen or a carboxylic acid group and B is a biomolecule selected from the group consisting of a peptide, a protein, a lipid, a carbohydrate and a polynucleotide. The biomolecule conjugated polymers can be disposed onto an electrically conductive substrate wherein the substrate has a first layer of PEDOT polymerized on a surface of the substrate and a second layer of biomolecule conjugated PEDOT polymer of Formula (III) polymerized on the first layer of PEDOT. The first and second layers form a charge transport material in electrical communication with the conductive substrate. The electrically conductive substrate further comprises a dopant.

Abstract translation: 对应于式（I）的导电羧酸官能化单体，其中A表示氢或羧基。 与生物分子缀合的式（I）的聚合单体导致式（III）的共轭PEDOT聚合物，其中A是氢或羧酸基团，B是选自肽，蛋白质，脂质的生物分子 ，碳水化合物和多核苷酸。 生物分子共轭聚合物可以设置在导电基底上，其中基底具有在基底表面上聚合的第一层PEDOT和在第一层PEDOT上聚合的式（III）的生物分子共轭PEDOT聚合物的第二层。 第一和第二层形成与导电基底电连通的电荷传输材料。 导电衬底还包括掺杂剂。