- 专利标题: Method of preparing acrylic polymers and products produced thereby
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申请号: US14366407申请日: 2012-12-17
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公开(公告)号: US09725589B2公开(公告)日: 2017-08-08
- 发明人: Wei-Yeih Yang
- 申请人: Lubrizol Advanced Materials, Inc.
- 申请人地址: US OH Cleveland
- 专利权人: Lubrizol Advanced Materials, Inc.
- 当前专利权人: Lubrizol Advanced Materials, Inc.
- 当前专利权人地址: US OH Cleveland
- 代理商 Thoburn T. Dunlap
- 国际申请: PCT/US2012/070113 WO 20121217
- 国际公布: WO2013/096206 WO 20130627
- 主分类号: C08L39/06
- IPC分类号: C08L39/06 ; C08L33/08 ; C08L33/10 ; C08L33/12 ; C08L33/02 ; C08F2/14 ; C08F2/08 ; C08F226/10 ; C08F265/02 ; C08F285/00 ; C08F222/02 ; C08F220/62 ; C08F220/04 ; C08F220/06 ; C08F120/04 ; C08F220/02 ; C08F120/08 ; C08F120/02 ; C08F120/06 ; C08F122/06 ; C08F122/04 ; C08F122/02 ; C08F271/02
摘要:
A process for preparing a composition by free-radical polymerization of a monomer composition comprising: a) at least one ethylenically unsaturated carboxylic acid containing monomer or anhydride thereof; b) optionally at least one ethylenically unsaturated monomer different from a) but copolymerizable therewith; and c) at least one crosslinking monomer containing at least two ethylenically unsaturated groups. The monomer composition is polymerized in an organic medium having a solubilizing effect on one or more of the monomeric ingredients, but substantially none on the resulting polymer. The polymerization is conducted in the presence of a free radical forming catalyst and at least one steric stabilizing polymer polymerized from a vinyl lactam and a copolymerizable monomer selected from a short chain alkyl ester of (meth)acrylic acid, a long chain alkyl ester of (meth)acrylic acid, and combinations thereof.
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