发明授权
- 专利标题: Chelating agent precursors, fluids containing them, and their use
- 专利标题(中): 螯合剂前体,含有它们的流体及其用途
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申请号: US14000675申请日: 2012-02-20
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公开(公告)号: US09556378B2公开(公告)日: 2017-01-31
- 发明人: James N. Lepage , Cornelia Adriana De Wolf , Johanna Hendrika Bemelaar , Adrianus Maria Reichwein , Axel Carstens , Edwin Rudolf Antony Bang
- 申请人: James N. Lepage , Cornelia Adriana De Wolf , Johanna Hendrika Bemelaar , Adrianus Maria Reichwein , Axel Carstens , Edwin Rudolf Antony Bang
- 申请人地址: NL Amersfoort
- 专利权人: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
- 当前专利权人: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
- 当前专利权人地址: NL Amersfoort
- 代理商 Sandra B. Weiss
- 优先权: EP11158650 20110317
- 国际申请: PCT/EP2012/052824 WO 20120220
- 国际公布: WO2012/113738 WO 20120830
- 主分类号: C09K8/86
- IPC分类号: C09K8/86 ; C07C227/18 ; C07C229/12 ; C07C229/24 ; C07C231/02 ; C07C237/06 ; C09K8/528
摘要:
The present invention relates to a chelating agent precursor that contains glutamic acid N,N-diacetic acid (GLDA) and/or methylglycine N,N-diacetic acid (MGDA) wherein at least one of the carboxylic acid groups is present as a carboxylic acid derivative selected from the group of amides, anhydrides, and esters, combinations thereof, and salts thereof, provided that it is not the triethyl ester of GLDA, the triethyl mono-t-butyl ester of GLDA, the tri-t-butyl ester of GLDA, the monobenzyl tri-t-butyl ester of GLDA, any ester or amide that contains azacycloalkane groups, any amide that contains biotin groups, any amide that contains minoethylcarbamoyl based amide groups, (S)-diethyl 2,2′-(1-benzyloxy)-1,5-dioxo-5-(prop-2-ynylamino)pentan-2-ylazanediyl-diacetate, diethyl 2,2′-(5-(3-azidopropylamino)-1-(benzyloxy)-1,5-dioxo-pentan-2-ylazanediyl-diacetate, the trimethyl ester of MGDA, the monomethyl ester dimethylamide of MGDA, the dibenzyl ester of MGDA, the dibenzyl mono t-butyl ester of MGDA, the di t-butyl ester of MGDA, the di-t-butyl-monobenzyl ester of MGDA, N,N-bis(benzyloxycarbonylmethyl)-N′-methoxycarbonyl-methyl-alanine amide, or N,N-bis(tert-butoxycarbonyl)-N′-methoxycarbonylmethyl-alanine amide, and esters of GLDA immobilized on a gel, and that the amide is not the amide of ammonia, to a fluid containing the above chelating precursor and a liquid, and to the use of a chelating agent precursor of MGDA and GLDA and fluids containing them in an application wherein delayed acidity or the chelating capacity is useful, such as in descaling, bleaching, cleaning, and treating oil and/or gas-containing subterranean formations.
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