Invention Grant
- Patent Title: Dual site catalyst for mild, selective nitrile reduction
- Patent Title (中): 用于轻度，选择性腈还原的双位点催化剂
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Application No.: US14948898Application Date: 2015-11-23
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Publication No.: US09403753B2Publication Date: 2016-08-02
- Inventor: Travis J. Williams , Zhiyao Lu
- Applicant: University of Southern California
- Applicant Address: US CA Los Angeles
- Assignee: University of Southern California
- Current Assignee: University of Southern California
- Current Assignee Address: US CA Los Angeles
- Agency: Brooks Kushman P.C.
- Main IPC: C07F15/00
- IPC: C07F15/00 ; C07D213/00 ; C07C209/00 ; C07C209/48 ; B01J31/18 ; C07C213/02 ; C07D213/38 ; C07D307/68 ; C07D333/38
Abstract:
A ruthenium bis(pyrazolyl)borate scaffold that enables cooperative reduction reactivity in which boron and ruthenium centers work in concert to effect selective nitrile reduction is provided. The pre-catalyst compound [κ3-(1-pz)2HB(N═CHCH3)]Ru(cymene)+ TfO− (pz=pyrazolyl) was synthesized using readily-available materials through a straightforward route, thus making it an appealing catalyst for a number of reactions.
Public/Granted literature
- US20160145193A1 DUAL SITE CATALYST FOR MILD, SELECTIVE NITRILE REDUCTION Public/Granted day:2016-05-26
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