发明授权
- 专利标题： Dual site catalyst for mild, selective nitrile reduction
- 专利标题（中）： 用于轻度，选择性腈还原的双位点催化剂
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申请号： US14948898申请日： 2015-11-23
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公开(公告)号： US09403753B2公开(公告)日： 2016-08-02
- 发明人: Travis J. Williams , Zhiyao Lu
- 申请人： University of Southern California
- 申请人地址： US CA Los Angeles
- 专利权人： University of Southern California
- 当前专利权人： University of Southern California
- 当前专利权人地址： US CA Los Angeles
- 代理机构： Brooks Kushman P.C.
- 主分类号： C07F15/00
- IPC分类号： C07F15/00 ; C07D213/00 ; C07C209/00 ; C07C209/48 ; B01J31/18 ; C07C213/02 ; C07D213/38 ; C07D307/68 ; C07D333/38
摘要：
A ruthenium bis(pyrazolyl)borate scaffold that enables cooperative reduction reactivity in which boron and ruthenium centers work in concert to effect selective nitrile reduction is provided. The pre-catalyst compound [κ3-(1-pz)2HB(N═CHCH3)]Ru(cymene)+ TfO− (pz=pyrazolyl) was synthesized using readily-available materials through a straightforward route, thus making it an appealing catalyst for a number of reactions.
公开/授权文献
- US20160145193A1 DUAL SITE CATALYST FOR MILD, SELECTIVE NITRILE REDUCTION 公开/授权日：2016-05-26
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