发明授权
- 专利标题: Fluorinated carbon composite cathode for a high-energy lithium battery
- 专利标题(中): 氟化碳复合阴极用于高能锂电池
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申请号: US13206895申请日: 2011-08-10
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公开(公告)号: US08961833B2公开(公告)日: 2015-02-24
- 发明人: Shengshui Zhang , Donald L. Foster , Jeffery Wolfenstine , Jeffery A. Read
- 申请人: Shengshui Zhang , Donald L. Foster , Jeffery Wolfenstine , Jeffery A. Read
- 申请人地址: US DC Washington
- 专利权人: The United States of America as represented by the Secretary of the Army
- 当前专利权人: The United States of America as represented by the Secretary of the Army
- 当前专利权人地址: US DC Washington
- 代理商 Avrom David Spevack; John H. Raubitschek
- 主分类号: H01B1/06
- IPC分类号: H01B1/06 ; H01M4/583 ; H01M4/62 ; H01M10/052 ; H01B1/00 ; H01B1/12 ; H01B1/24
摘要:
A lithium/fluorinated carbon (Li/CFx) battery having a composite cathode including an electroactive cathode material, a non-electroactive additive, a conductive agent, and a binder. The electroactive cathode material is a single fluorinated carbon having a general formula of CFx, whereby x is an averaged value ranging from about 0.5 to about 1.2. The non-electroactive additive is at least one or a mixture of two or more oxides selected from the group comprising Mg, B, Al, Si, Cu, Zn, Y, Ti, Zr, Fe, Co, or Ni. The conductive agent is selected from the group comprising carbon, metals, and mixtures thereof. Finally, the binder is an amorphous polymer selected from the group comprising fluorinated polymers, ethylene-propylene-diene (EPDM) rubbers, styrene butadiene rubbers (SBR), poly (acrylonitrile-methyl methacrylate), carboxymethyl celluloses (CMC), and polyvinyl alcohol (PVA). Also, a method of reducing the initial voltage drop of a lithium/fluorinated carbon (Li/CFx) battery by providing a composite cathode which includes an electroactive cathode material having a general formula of CFx, whereby x is an averaged value ranging from about 0.5 to about 1.2, a non-electroactive additive, a conductive agent, and a binder.
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