A non-destructive assay of deactivation of the contents of explosives and chemical warfare on-field (and or in lab) is presented with high-energy neutrons at 14, 4 and 2 MeV. The elements and substances present in the munitions are transmuted into passive elements through neutron-alpha nuclear reactions. Deactivating of the explosives on-field is presented with a unique and compact neutron generator fueled with deuterium gas and tritium breeder. Several high explosives and chemical warfare are presented in the transmutation with physical analysis. The present method and technique can be employed on-field as an improvised explosive device and as a precise explosive device in labs and centers.