发明授权
- 专利标题: Process for preparing a cyclic tertiary methylamine
- 专利标题(中): 制备环状叔甲胺的方法
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申请号: US13158667申请日: 2011-06-13
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公开(公告)号: US08637668B2公开(公告)日: 2014-01-28
- 发明人: Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein , Harald Meiβner
- 申请人: Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein , Harald Meiβner
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 代理机构: Novak Druce Connolly Bove + Quigg LLP
- 主分类号: C07D295/03
- IPC分类号: C07D295/03
摘要:
Process for preparing a cyclic tertiary methylamine of the formula I where A is a C4-alkylene group, a C5-alkylene group or a —(CH2)2—B—(CH2)2— group, where B is oxygen (O) or an N—R1 radical and R1 is C1-C5-alkyl, aryl or C5-C7-cycloalkyl, wherein an amino alcohol II from the group consisting of 1,4-aminobutanol, 1,5-aminopentanol, aminodiglycol (ADG) or aminoethylethanolamine of the formula IIa where R1 is as defined above or is hydrogen (H), in which case R1═CH3 in the amine I, is reacted with methanol in a reactor at a temperature in the range from 150 to 270° C. in the liquid phase in the presence of a copper-comprising heterogeneous catalyst.
公开/授权文献
- US20120157679A1 PROCESS FOR PREPARING A CYCLIC TERTIARY METHYLAMINE 公开/授权日:2012-06-21
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