发明授权
- 专利标题: Method for processing Fischer-Tropsch off-gas
- 专利标题(中): 费 - 托废气处理方法
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申请号: US13660895申请日: 2012-10-25
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公开(公告)号: US08632697B2公开(公告)日: 2014-01-21
- 发明人: Justus Theodorus Gerardus Te Braake , Maarten Bracht , Desmond Andrew Bungku , Wouter David Van De Graaf , Xander Linders , Sivakumar Sadasivan Vijayakumari
- 申请人: Shell Oil Company
- 申请人地址: US TX Houston
- 专利权人: Shell Oil Company
- 当前专利权人: Shell Oil Company
- 当前专利权人地址: US TX Houston
- 优先权: EP11186512 20111025; EP11186516 20111025
- 主分类号: C01B3/50
- IPC分类号: C01B3/50
摘要:
A method for producing a gas comprising at least 80 vol % carbon monoxide from a Fischer-Tropsch off-gas comprising: (1) feeding Fischer-Tropsch off-gas through a column comprising an adsorbent bed at high pressure and discharging effluent; (2) reducing the pressure in the column and the bed slightly; (3) rinsing the column and the adsorbent bed with methane or carbon dioxide; (4) rinsing the column and the adsorbent bed with carbon dioxide; (5) reducing the pressure of the column and adsorbent bed to a low pressure; (6) rinsing the column and adsorbent bed with a mixture of hydrogen and nitrogen; (7) pressurizing the column and adsorbent bed to a high pressure using a mixture of hydrogen and nitrogen. The carbon monoxide rich product stream obtained in step (3) can be sent as feed to a Fischer-Tropsch reaction. In an embodiment, a gas comprising at least 80 vol % hydrogen is also produced.
公开/授权文献
- US20130099167A1 METHOD FOR PROCESSING FISCHER-TROPSCH OFF-GAS 公开/授权日:2013-04-25
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