Invention Grant
US08604149B2 Polysilane-polycarbosilane copolymer solutions and oxygen-depleted ceramic moulded bodies prepared therefrom with compositions similar to that of SiC
有权
聚硅烷 - 聚碳硅烷共聚物溶液和由其制备的具有类似于SiC的组成的贫氧陶瓷成型体
- Patent Title: Polysilane-polycarbosilane copolymer solutions and oxygen-depleted ceramic moulded bodies prepared therefrom with compositions similar to that of SiC
- Patent Title (中): 聚硅烷 - 聚碳硅烷共聚物溶液和由其制备的具有类似于SiC的组成的贫氧陶瓷成型体
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Application No.: US11579278Application Date: 2005-05-02
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Publication No.: US08604149B2Publication Date: 2013-12-10
- Inventor: Juergen Clade , Erich Seider , Dieter Sporn , Erika Brendler , Thomas Lange , Gerhard Roewer , Dorit Mainhold
- Applicant: Juergen Clade , Erich Seider , Dieter Sporn , Erika Brendler , Thomas Lange , Gerhard Roewer , Dorit Mainhold
- Applicant Address: DE Munich
- Assignee: Fraunhofer-Gesellschaft zur Foerderung der angewandten Forschung e.V.
- Current Assignee: Fraunhofer-Gesellschaft zur Foerderung der angewandten Forschung e.V.
- Current Assignee Address: DE Munich
- Agency: Duane Morris LLP
- Priority: DE102004021666 20040503; DE102004042531 20040902
- International Application: PCT/EP2005/004754 WO 20050502
- International Announcement: WO2005/108470 WO 20051117
- Main IPC: C04B35/80
- IPC: C04B35/80 ; C08L83/16 ; B28B1/00 ; C08G77/60 ; D01F9/10 ; C04B35/622

Abstract:
The invention relates to a method for producing a polysilane-polycarbosilane copolymer solution. Said method comprises the preparation of a polysilane, obtained by the disproportionation of a methylchlorodisilane or a mixture of methylchlorodisilanes of formula Si2MenC16-n with a Lewis base as the catalyst, a subsequent thermal cross-linking of the polysilane to form an infusible polysilane-polycarbosilane copolymer that is soluble in inert solvents, in addition to the production of said solution by the dissolution of the polysilane-polycarbosilane copolymer in an inert solvent. The invention also relates to a method for producing oxygen-depleted ceramic fibers and other molded bodies with a composition similar to that of SiC. Said method comprises the spinning of the solution to obtain green fibers according to the dry spinning method and the pyrolysis of the dried green fibers in an inert gas atmosphere or a reductive atmosphere.
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