发明授权
- 专利标题: Semi continuous operational method for producing copolymers
- 专利标题(中): 用于生产共聚物的半连续操作方法
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申请号: US12920143申请日: 2009-02-10
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公开(公告)号: US08541518B2公开(公告)日: 2013-09-24
- 发明人: Gerhard Albrecht , Klaus Lorenz , Christian Scholz , Petra Wagner
- 申请人: Gerhard Albrecht , Klaus Lorenz , Christian Scholz , Petra Wagner
- 申请人地址: DE Trostberg
- 专利权人: Construction Research & Technology GmbH
- 当前专利权人: Construction Research & Technology GmbH
- 当前专利权人地址: DE Trostberg
- 代理机构: Curatolo Sidoti Co., LPA
- 代理商 Joseph G. Curratolo; Salvatore A. Sidoti
- 优先权: EP08102758 20080319
- 国际申请: PCT/EP2009/051481 WO 20090210
- 国际公布: WO2009/115371 WO 20090924
- 主分类号: C08F2/04
- IPC分类号: C08F2/04 ; C08F224/00 ; C08F2/10 ; C04B28/28
摘要:
A process for the preparation of a copolymer in a semicontinuous mode of operation in a polymerization apparatus containing a polymerization reactor connected to a metering device, in each case acid monomer being initially introduced into the metering device and polyether macromonomer and water into the polymerization reactor, acid monomer being metered from the metering device into the polymerization reactor, the metering of the acid monomer into the polymerization reactor being effected in such a way that first a polymerization pH is established in the aqueous medium and then, until the conversion of 70 mol % of the polyether macromonomer initially introduced into the polymerization reactor, acid monomer is passed into the polymerization reactor in an amount per unit time such that the pH in the aqueous medium deviates by not more than ±0.3 from the initially established polymerization pH.
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