发明授权
US08497316B2 Crosslinkable and foaming polyester-polyurethane (hybrid) resin moulding compositions, with foaming characteristics for closed mould applications
有权
交联和发泡聚酯 - 聚氨酯(混合)树脂模塑组合物,具有闭模应用的发泡特性
- 专利标题: Crosslinkable and foaming polyester-polyurethane (hybrid) resin moulding compositions, with foaming characteristics for closed mould applications
- 专利标题(中): 交联和发泡聚酯 - 聚氨酯(混合)树脂模塑组合物,具有闭模应用的发泡特性
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申请号: US12682499申请日: 2008-09-29
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公开(公告)号: US08497316B2公开(公告)日: 2013-07-30
- 发明人: Paul Darby , Phil Dean
- 申请人: Paul Darby , Phil Dean
- 申请人地址: GB North East Lincolnshire
- 专利权人: CCP Composites UK Ltd
- 当前专利权人: CCP Composites UK Ltd
- 当前专利权人地址: GB North East Lincolnshire
- 代理机构: Whyte Hirschboeck Dudek S.C.
- 优先权: EP07254003 20071009
- 国际申请: PCT/EP2008/008281 WO 20080929
- 国际公布: WO2009/046902 WO 20090416
- 主分类号: A63B37/02
- IPC分类号: A63B37/02 ; B22C1/22 ; B29C44/12 ; B29C65/00 ; B32B27/00 ; B32B27/40 ; B60J9/00 ; B62C1/00 ; B62D23/00 ; B23D39/00 ; C04B26/06 ; C08F8/30 ; C08F20/00 ; C08F283/04 ; C08G18/00 ; C08G18/08 ; C08G18/28 ; C08G18/42 ; C08G63/00 ; C08G73/00 ; C08J9/00 ; C08J9/12 ; C08J9/30 ; C08K3/10 ; C08K3/26 ; C08L47/00 ; C08L51/00 ; C08L67/00 ; C08L75/00 ; C08L77/00 ; C09D17/00 ; E04C1/00
摘要:
It concerns a crosslinkable and foaming polyester-polyurethane resin moulding composition, comprising: an A component, comprising: A1) at least one poly-functional isocyanate compound, and A2) at least one free radical polymerization initiator a B component, comprising by weight: B1) 100 parts of at least one polyol resin comprising: —B11) 50 to 80 parts of at least one ethylenically unsaturated polyester polyol—B 12) 20 to 50 parts of at least one ethylenically unsaturated monomer, with, B11), being the reaction product of: a) an acid component comprising: a1) at least one ethylenically unsaturated diacid, and a2) at least one saturated diacid with a1/a2 molar ratio so varying to have an unsaturation content in B11) from 0.25/1 to 5/1, and, b) a diol component in excess with respect to component a) B2) from 0.01 to 1.1 parts of water, B3) optionally, up to 35% of at least one hydroxy alkyl (meth)acrylate, B4) at least one catalyst of the isocyanate/hydroxyl reaction, B5) at least one accelerator for the free radical initiator decomposition, B6) at least one foam stabilizer, B7) optionally, fillers and/or other additives the said composition being free of any primary or of secondary amine and of any polyol of low Mw chain extender. The invention further relates to a process of preparation and specific uses in light weight articles in sanitary, building or automotive uses.
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