发明授权
- 专利标题: Method for transitioning between incompatible olefin polymerization catalyst systems
- 专利标题(中): 在不相容烯烃聚合催化剂体系之间转化的方法
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申请号: US13133803申请日: 2009-12-17
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公开(公告)号: US08481658B2公开(公告)日: 2013-07-09
- 发明人: Gerhardus Meier , Shahram Mihan
- 申请人: Gerhardus Meier , Shahram Mihan
- 申请人地址: DE Wesseling
- 专利权人: Basell Polyolefine GmbH
- 当前专利权人: Basell Polyolefine GmbH
- 当前专利权人地址: DE Wesseling
- 优先权: EP08022359 20081223
- 国际申请: PCT/EP2009/009066 WO 20091217
- 国际公布: WO2010/072367 WO 20100701
- 主分类号: C08F255/00
- IPC分类号: C08F255/00 ; C08F4/64 ; C08F2/34 ; C08F4/24
摘要:
A method for transitioning from a Ziegler-Natta to a Phillips catalyst system for the olefin polymerization reaction in one reactor, preferably a gas phase reactor, is described. The method comprises the steps of a) discontinuing a first olefin polymerization reaction performed in the presence of the Ziegler-Natta catalyst system; b) performing a second olefin polymerization reaction in the presence of a further catalyst system comprising catalyst components (A) and (B) producing, respectively, a first and a second polyolefin fraction, wherein the Mw of the first polyolefin fraction is less than the Mw of the second polyolefin fraction and the initial activity of catalyst component (A) exceeds the initial activity of catalyst component (B); and c) performing a third olefin polymerization reaction the presence of the Phillips catalyst system. Thanks to this method, there is no need to empty the reactor after each olefin polymerization reaction, and the transitioning time needed to attain the desired quality of the polyolefin obtained in each olefin polymerization reaction subsequent to the first one is sufficiently short to permit a quick and reliable change of production.
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