发明授权
- 专利标题: Olefin functionalization by metathesis reaction
- 专利标题(中): 烯烃通过复分解反应进行功能化
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申请号: US12488093申请日: 2009-06-19
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公开(公告)号: US08283419B2公开(公告)日: 2012-10-09
- 发明人: John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, Jr. , Donna J. Crowther , Patrick Brant
- 申请人: John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, Jr. , Donna J. Crowther , Patrick Brant
- 申请人地址: US TX Houston
- 专利权人: ExxonMobil Chemical Patents Inc.
- 当前专利权人: ExxonMobil Chemical Patents Inc.
- 当前专利权人地址: US TX Houston
- 代理商 Catherine L. Bell
- 主分类号: C08F255/00
- IPC分类号: C08F255/00 ; C08F255/02 ; C08F210/06 ; C08F110/06
摘要:
This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)−83), when 70 to 90 mol % ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum.
公开/授权文献
- US20090318647A1 Olefin Functionalization By Metathesis Reaction 公开/授权日:2009-12-24
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