发明授权
US08268949B2 Borohydride metallocene complex of a lanthanide, catalytic system including the said complex, polymerisation method using same and ethylene/butadiene copolymer obtained using said method
有权
镧系元素的硼氢化物茂金属络合物,包括所述络合物的催化体系,使用其的聚合方法和使用所述方法获得的乙烯/丁二烯共聚物
- 专利标题: Borohydride metallocene complex of a lanthanide, catalytic system including the said complex, polymerisation method using same and ethylene/butadiene copolymer obtained using said method
- 专利标题(中): 镧系元素的硼氢化物茂金属络合物,包括所述络合物的催化体系,使用其的聚合方法和使用所述方法获得的乙烯/丁二烯共聚物
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申请号: US13290617申请日: 2011-11-07
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公开(公告)号: US08268949B2公开(公告)日: 2012-09-18
- 发明人: Julien Thuilliez , Christophe Boisson , Roger Spitz
- 申请人: Julien Thuilliez , Christophe Boisson , Roger Spitz
- 申请人地址: CH Granges-Paccot FR Puteaux FR Paris FR Cedex
- 专利权人: Michelin Recherche et Technique S.A.,Total Petrochemicals France,Centre National de la Recherche Scientifique,Ecole Superieure de Chimie-Physique-Electronique de Lyon
- 当前专利权人: Michelin Recherche et Technique S.A.,Total Petrochemicals France,Centre National de la Recherche Scientifique,Ecole Superieure de Chimie-Physique-Electronique de Lyon
- 当前专利权人地址: CH Granges-Paccot FR Puteaux FR Paris FR Cedex
- 代理机构: Cozen O'Connor
- 优先权: FR0511393 20051109
- 主分类号: C08F236/06
- IPC分类号: C08F236/06 ; C08F4/52
摘要:
Borohydride metallocene complex of lanthanide, preparation process, catalytic system incorporating it, copolymerization of olefins employing catalytic system and ethylene/butadiene copolymer, the butadiene units comprise 1,2-cyclohexane or 1,2- and 1,4-cyclohexane links. The complex corresponds to of formulae A and/or B: where, in A two ligands Cp1 and Cp2, each of a fluorenyl group, are connected to the lanthanide Ln, where, in B, a ligand molecule, composed of two fluorenyl groups Cp1 and Cp2 are connected via bridge P of formula MR1R2, is an element from group IVa, R1 and R2, which are identical or different, represent an alkyl group comprising from 1 to 20 carbon atoms, connected to lanthanide Ln, L is alkali metal, N is molecule of a complexing solvent, x is integral or non-integral number ≧0 and p is integer ≧1.
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