发明授权
US08178718B2 Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
有权
用于将饱和和不饱和醛氧化成不饱和羧酸的催化剂,其制备方法及其使用方法
- 专利标题: Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
- 专利标题(中): 用于将饱和和不饱和醛氧化成不饱和羧酸的催化剂,其制备方法及其使用方法
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申请号: US11702395申请日: 2007-02-05
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公开(公告)号: US08178718B2公开(公告)日: 2012-05-15
- 发明人: Wugeng Liang , Paul E. Ellis , Joseph R. Linzer
- 申请人: Wugeng Liang , Paul E. Ellis , Joseph R. Linzer
- 申请人地址: SA Riyadh
- 专利权人: Saudi Basic Industries Corporation
- 当前专利权人: Saudi Basic Industries Corporation
- 当前专利权人地址: SA Riyadh
- 代理机构: Cantor Colburn LLP
- 主分类号: C07C51/235
- IPC分类号: C07C51/235 ; B01J23/887
摘要:
The invention is a supported or bound heteropoly acid catalyst composition, a method of making the catalyst composition and a process for the oxidation of saturated and/or unsaturated aldehydes to unsaturated carboxylic acids using the catalyst composition. The catalyst composition has a heteropoly acid component containing molybdenum, vanadium, phosphorus and cesium and support/binder having a surface area of about 0.1 m2/g to about 1.0 m2/g. The catalyst is made by dissolving compounds of the components of each of the heteropoly acid compounds in a solution, precipitating the heteropoly acid compounds, contacting the heteropoly acid compounds to form a catalyst precursor and calcining the catalyst precursor to form a heteropoly acid compound catalyst. Unsaturated aldehydes, such as methacrolein, may be oxidized in the presence of the heteropoly acid compound catalyst to produce an unsaturated carboxylic acid, such as methacrylic acid.
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