发明授权
- 专利标题： Fluoroamine having perfluoroalkyl group, process for producing the same, method of fluorination therewith, and method of recovering amide having perfluoroalkyl group
- 专利标题（中）： 具有全氟烷基的氟胺，其制造方法，其氟化方法以及回收具有全氟烷基的酰胺的方法
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申请号： US12302362申请日： 2007-05-31
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公开(公告)号： US08093429B2公开(公告)日： 2012-01-10
- 发明人: Toshio Hidaka , Takafumi Yoshimura , Shoji Hara , Tsuyoshi Fukuhara
- 申请人： Toshio Hidaka , Takafumi Yoshimura , Shoji Hara , Tsuyoshi Fukuhara
- 申请人地址： JP Hokkaido JP Tokyo
- 专利权人： National University Corporation Hokkaido University,Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人： National University Corporation Hokkaido University,Mitsubishi Gas Chemical Company, Inc.
- 当前专利权人地址： JP Hokkaido JP Tokyo
- 代理机构： Antonelli, Terry, Stout & Kraus, LLP.
- 优先权： JP2006-152140 20060531
- 国际申请： PCT/JP2007/061075 WO 20070531
- 国际公布： WO2007/139182 WO 20071206
- 主分类号： C07C211/27
- IPC分类号： C07C211/27
摘要：
Provided are a fluorous-tag-introduced fluoroamine of a general formula (I), its production method, a method of fluorination of a substrate having functional group containing oxygen with the fluoroamine serving as a fluorinating agent, and a method of recovering a fluorous-tag-introduced amide after the fluorination. The fluoroamine and its production method, as well as the fluorination method with the fluoroamine and the method of recovery of a fluorous-tag-introduced amide are ecological and advantageous in industrial use, as the load for separating and collecting the product after the fluorination with the fluoroamine serving as a fluorinating agent is small. (In the formula, R0 is an alkyl group or an aryl group having substituent(s) of Rf—(CH2)m—; Rf is a perfluoroalkyl group; m is from 0 to 2; R1 and R2 each are an alkyl group or an aryl group.)
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