发明授权
US07977499B2 Bis(ferrocenylphosphino) ferrocene ligands used in asymmetric hydrogenation reactions
失效
用于不对称氢化反应的双(二茂铁基膦基)二茂铁配体
- 专利标题: Bis(ferrocenylphosphino) ferrocene ligands used in asymmetric hydrogenation reactions
- 专利标题(中): 用于不对称氢化反应的双(二茂铁基膦基)二茂铁配体
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申请号: US12449638申请日: 2008-02-15
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公开(公告)号: US07977499B2公开(公告)日: 2011-07-12
- 发明人: Weiping Chen , Felix Spiindler , Ulrike Nettekoven , Benoît Pugin
- 申请人: Weiping Chen , Felix Spiindler , Ulrike Nettekoven , Benoît Pugin
- 申请人地址: CH Basel
- 专利权人: Solvias AG
- 当前专利权人: Solvias AG
- 当前专利权人地址: CH Basel
- 代理机构: Wenderoth, Lind & Ponack, L.L.P.
- 优先权: CH0282/07 20070220
- 国际申请: PCT/EP2008/051836 WO 20080215
- 国际公布: WO2008/101868 WO 20080828
- 主分类号: C07F15/00
- IPC分类号: C07F15/00 ; C07C57/30
摘要:
Abstract Compounds of the formula (I) in the form of racemates, enantiomerically pure diastereomers or a mixture of diastereomers, where the radicals R1 are identical or different and are each C1-C4-alkyl; m is 0 or an integer from 1 to 4; n is 0 or an integer from 1 to 3; p is 0 or an integer from 1 to 5; R2 is an aromatic hydrocarbon radical or a C-bonded heterohydrocarbon radical and R3 is an aliphatic or C-bonded heteroaliphatic hydrocarbon radical; R2 and R3 are identical or different and are each an aliphatic or C-bonded heteroaliphatic hydrocarbon radical; R4 is an unsubstituted or C1-C6-alkyl-, C1-C6-alkoxy- or halogen-substituted hydrocarbon radical; and A is a secondary amino group, are ligands for metal complexes which are suitable as catalysts for homogeneous enantioselective hydrogenation.
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