发明授权
US07910671B2 Linear perfluoropolyethers having an improved thermooxidative stability 有权
具有改善的热氧化稳定性的线性全氟聚醚

Linear perfluoropolyethers having an improved thermooxidative stability
摘要:
Linear perfluoropolyethers of formula: T-O(CF2O)n(CF2CF2O)m(CF2CF2CF2O)r(CF2CF2CF2CF2O)s-T1  (I) wherein n, m, r, s are integers such that the polymer number average molecular weight is comprised between 700 and 100,000 and the n/(n+m+r+s) ratio ranges from 0.05 to 0.40, and respective preparation process by addition of a peroxidic perfluoropolyether of formula (III): T4-O(CF2O)n′(CF2CF2O)m′(O)h-T5  (III) having a PO from 1.8 to 4, to a perfluoropolyether oil preheated at a temperature comprised between 150° C. and 250° C. and subsequent exhaustive fluorination of the obtained compound.
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