A solar cell assembly includes a first solar cell panel, a second solar cell panel, and at least one light guide assembly. The first solar cell panel has at least one first through hole defined therein. The second solar cell panel faces and is spaced from the first solar cell panel. The at least one light guide assembly comprises a light diverging lens engaged in the first through hole of the first solar cell panel, and a light guide body aligned with the light diverging lens and located between the first and second solar cell panels. The light diverging lens is configured for diverging sunlight incident thereupon and forming diverged light. The light guide body has an incident surface for receiving the diverged light, and emitting surfaces for emitting light to the second solar cell panel.