发明授权
- 专利标题: Process for preparing TCD-diamine
- 专利标题(中): 制备TCD-二胺的方法
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申请号: US10967597申请日: 2004-10-18
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公开(公告)号: US07317128B2公开(公告)日: 2008-01-08
- 发明人: Peter Lappe , Helmut Springer , Rainer Lukas
- 申请人: Peter Lappe , Helmut Springer , Rainer Lukas
- 申请人地址: DE Oberhausen
- 专利权人: Oxea Deutschland GmbH
- 当前专利权人: Oxea Deutschland GmbH
- 当前专利权人地址: DE Oberhausen
- 代理商 Charles A. Muserlian
- 优先权: DE10352258 20031108
- 主分类号: C07C209/00
- IPC分类号: C07C209/00
摘要:
A process for preparing 3(4),8(9)-bis(aminomethyl)tricycle-[5.2.1.02,6]decane by hydroformylating dicyclopentadiene with subsequent reductive amination wherein the hydroformylation of dicyclopentadiene is carried out in two stages, and, in a first hydroformylation stage, the reaction is effected in a heterogeneous reaction system using an aqueous solution of transition metal compounds, containing water-soluble organic phosphorus (III) compounds in complex-bound form, of group VIII of the Periodic Table to give 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene, and, in a second hydroformylation stage, the thus obtained 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene is converted, in a homogeneous organic phase in the presence of transition metal compounds of group VIII of the Periodic Table of the Elements to 3(4),8(9)-bisformyltricyclo[5.2.1.02,6]decane
公开/授权文献
- US20050101796A1 Process for preparing TCD-diamine 公开/授权日:2005-05-12
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