A tight buffered optical fiber having a protective layer generally surrounding the optical fiber, a release layer at least partially bonding to and generally surrounding the protective layer and a buffer layer generally surrounding and being strippable from the release layer. The release layer including an acrylate with oligomers, monomers and a reactive release substance distributed with a matrix. The reactive release substance may include a silicone selected from the group including methyl and phenyl silicones. The matrix may be mechanically or chemically bonded to the protective layer so that stripping the buffer layer does not remove the release layer.