发明授权
- 专利标题: High temperature viscosity stable thickener
- 专利标题(中): 高温粘度稳定增稠剂
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申请号: US09133691申请日: 1998-08-13
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公开(公告)号: US06762269B1公开(公告)日: 2004-07-13
- 发明人: Joseph S. Maxim, Jr. , James C. Long , Daniel W. Verstrat
- 申请人: Joseph S. Maxim, Jr. , James C. Long , Daniel W. Verstrat
- 主分类号: C08F21616
- IPC分类号: C08F21616
摘要:
A hydrophobe-containing alkali soluble or swellable copolymer thickener comprising an emulsion polymerization product of (A) an ethylenically unsaturated copolymerizable surfactant monomer having a cloud point of from about 65° C. to about 95° C., wherein the surfactant monomer has the formula M(EO)x(BO)zOR1 wherein M is a residue selected from the group consisting of an ethylenically unsaturated carboxylic acid, and an ethylenically unsaturated dicarboxylic acid, EO is an ethylene oxide unit; BO is a butylene oxide unit; x is from 10 to 45; z is from 5 to 35; provided that x+z is from 20 to 45; and R1 is selected from the group consisting of alkyl, alkylene, cycloalkyl, cycloalkylene, and arylalkyl group wherein the alkyl group has 1 to 4 carbon atoms; (B) an &agr;,&bgr;-ethylenically unsaturated monocarboxylic acid monomer; and (C) a nonionic &agr;,&bgr;-ethylenically unsaturated monomer. The copolymer provides aqueous compositions with constant or increased viscosity at temperatures approaching 120° C.
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