发明授权
- 专利标题: Method for controlled free radical polymerization or copolymerization of ethylene under high pressure in the presence of an initiator-controller
- 专利标题(中): 在引发剂 - 控制剂存在下,在高压下控制乙烯自由基聚合或共聚的方法
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申请号: US09807147申请日: 2001-06-15
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公开(公告)号: US06734269B1公开(公告)日: 2004-05-11
- 发明人: Michael Buback , Eric Minaux , Thierry Senninger , Jean-Marc Le Blevec
- 申请人: Michael Buback , Eric Minaux , Thierry Senninger , Jean-Marc Le Blevec
- 优先权: FR9812477 19981006; FR9910198 19990805
- 主分类号: C08F400
- IPC分类号: C08F400
摘要:
The present invention relates to a process for the radical polymerization or copolymerization of ethylene under high pressure in the presence of at least one polymerization initiating-controlling compound capable of providing, by decomposition under the polymerization or copolymerization conditions: at least one initiating free radical (Z) which carries at least one site for initiating the (co)polymerization; and at least one stable free radical (SFR) which carries at least one site exhibiting the stable radical state and which is stable under the polymerization conditions, with, in total, as many initiating sites as sites exhibiting the stable radical state.
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