Supported catalysts containing a platinum metal and process for preparing diaryl carbonates

发明授权

US06548445B1 Supported catalysts containing a platinum metal and process for preparing diaryl carbonates 失效

标题翻译：含铂金属的载体催化剂和制备碳酸二芳基酯的方法

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专利标题： Supported catalysts containing a platinum metal and process for preparing diaryl carbonates
专利标题（中）： 含铂金属的载体催化剂和制备碳酸二芳基酯的方法
申请号： US08625613

申请日： 1996-03-29
公开(公告)号： US06548445B1

公开(公告)日： 2003-04-15
发明人: Hans-Josef Buysch , Carsten Hesse , Jörg-Dietrich Jentsch , Johann Rechner , Eberhard Zirngiebl
申请人： Hans-Josef Buysch , Carsten Hesse , Jörg-Dietrich Jentsch , Johann Rechner , Eberhard Zirngiebl
优先权： DE19512615 19950405
主分类号： B01J2713
IPC分类号： B01J2713

Supported catalysts containing a platinum metal and process for preparing diaryl carbonates

摘要：

In the process for preparing an aromatic carbonate from an aromatic hydroxy compound, CO and O2 in the presence of a quaternary salt and a base using a platinum metal catalyst and a cocatalyst, use is advantageously made of supported catalysts containing, in the reaction-ready state, (i) a platinum metal, a platinum metal halide or a platinum metal halide complex and (ii) a metal compound acting as cocatalyst from groups IB, IIB, IIIA, IIIB, IVA, IVB, VB, VIB, VIIB, the iron group (atomic numbers 26-28) or the rare earth metals (atomic numbers 58-71) of the Periodic Table of the Elements (Mendeleev), each in an amount of 0.01-15% by weight, calculated as metal and based on the total weight of the catalyst.

摘要（中）：

在使用铂金属催化剂和助催化剂的季盐和碱的存在下，由芳族羟基化合物，CO和O 2制备芳香族碳酸酯的方法中，有利地由负载型催化剂制成，状态，（i）铂金属，铂金属卤化物或铂金属卤化物络合物和（ii）作为IB，IIB，IIIA，IIIB，IVA，IVB，VB，VIB，VIIB族的助催化剂的金属化合物，元素周期表（Mendeleev）的铁族（原子数26-28）或稀土金属（原子数58-71），其量为0.01-15％（重量），以金属计算，基于催化剂的总重量。

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