Homeotropic liquid crystal displays, and methods for their production and use, are provided. The alignment layers of the subject displays have at least one alignment structure rising from a planar substrate. At least a portion of the wall has a bond anisotropy sufficient to align liquid crystal molecules substantially vertical to the planar substrate of the alignment layer. The subject displays find use in a variety of different applications, including in monitors for use in laptop computers, desktop computers, televisions, and the like.