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US6110438A Method of making black phosphorus from red phosphorus 失效
红磷制黑磷的方法

Method of making black phosphorus from red phosphorus
Abstract:
The specification describes a method for producing black phosphorus from red phosphorus by thermally cycling red phosphorus in a vacuum between 360-400.degree. C. and 200-240.degree. C., whereupon the red phosphorous undergoes an allotropic phase change to black phosphorus.
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