发明授权
- 专利标题: Epoxidation process for aryl allyl ethers
- 专利标题(中): 芳基烯丙基醚的环氧化工艺
-
申请号: US316854申请日: 1999-05-21
-
公开(公告)号: US6087513A公开(公告)日: 2000-07-11
- 发明人: Zeng K. Liao , Clinton J. Boriack
- 申请人: Zeng K. Liao , Clinton J. Boriack
- 申请人地址: MI Midland
- 专利权人: The Dow Chemical Company
- 当前专利权人: The Dow Chemical Company
- 当前专利权人地址: MI Midland
- 主分类号: C07D301/03
- IPC分类号: C07D301/03 ; C07D301/19 ; C07D303/22 ; C07D303/23 ; C07D303/24
摘要:
A process for making an aromatic glycidyl ether epoxy compound by contacting an allyl ether made from the hydroxy moiety of a hydroxy-containing aromatic compound with an inorganic or organic hydroperoxide oxidant in the presence of a transition metal complex catalyst, wherein at least (a) the allyl ether is conformationally restricted or (b) the transition metal complex catalyst contains at least one or more stable ligands attached to the transition metal. The process of the present invention provides for epoxidizing aryl allyl ethers with high epoxidation yield (for example, greater than 70% to 90%) and high hydroperoxide selectivity (for example, greater than 70% to 90%).
公开/授权文献
- US4962641A Pulse jet engine 公开/授权日:1990-10-16
信息查询