A high temperature resistant oil containment boom having a protective cover, the cover comprising, in laminar combination, an outer layer of high temperature resistant metallic fabric, a first underlayer of high temperature resistant insulation, a second underlayer of a polymer-coated fabric, a third underlayer of high temperature resistant insulation and a bottom layer of a high temperature resistant polymer-coated material, the protective cover being unified by having at least the top and bottom layers secured together along their peripheral edges.