发明授权
US5164365A 1,1,2,3,3,6-hexamethyl-4,5,6,7-tetrahydro-5-indanone and fragrance compositions containing same 失效
1,1,2,3,3,6-十六烷基-4,5,6,7-四氢-2H-吲哚及其含有的芳香族组合物

1,1,2,3,3,6-hexamethyl-4,5,6,7-tetrahydro-5-indanone and fragrance
compositions containing same
摘要:
The present invention concerns the novel odorant 1,1,2,3,3,6-hexamethyl-4,5,6,7-tetrahydro-5-indanone, I, a process for the manufacture of I, novel intermediates used in the process and fragrance compositions containing I. ##STR1## The process for the manufacture of 1,1,2,3,3,6-hexamethyl-4,5,6,7-tetrahydro-5-indanone comprises hydroborating 1,1,2,3,3,6-hexamethyl-4,7-dihydroindane and oxidizing the hydroboration product to 1,1,2,3,3,6-hexamethyl-4,5,6,7-tetrahydro-5-indanone, or reductively alkylating, especially methylating, 5-nitro-1,1,2,3,3,6-hexamethylindane and converting the resulting 5-dialkyl-amino-1,1,2,3,3,6-hexamethylindane into 1,1,2,3,3,6-hexamethyl-4,5,6,7-tetrahydro-5-indanone by reduction of the benzene ring and hydrolysis of the resulting enamine.
公开/授权文献
信息查询
0/0