Invention Grant
- Patent Title: Process for producing a modified styrene polymer
- Patent Title (中): 制备改性苯乙烯聚合物的方法
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Application No.: US288981Application Date: 1988-12-22
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Publication No.: US4912170APublication Date: 1990-03-27
- Inventor: Tadashi Niwa , Masayuki Kato , Yoshio Taguchi , Chihiro Imai , Tokuo Makishima, deceased , by Nobuko Makishima, legal representative
- Applicant: Tadashi Niwa , Masayuki Kato , Yoshio Taguchi , Chihiro Imai , Tokuo Makishima, deceased , by Nobuko Makishima, legal representative
- Applicant Address: JPX Tokyo
- Assignee: Toa Nenryo Kogyo K.K.
- Current Assignee: Toa Nenryo Kogyo K.K.
- Current Assignee Address: JPX Tokyo
- Main IPC: C08F8/42
- IPC: C08F8/42 ; C08F8/00
Abstract:
This invention relates to a p-methyl styrene polymer represented by the following formula: ##STR1## Z denotes a group such as a functional group. Poly p-methylstyrene (PPMS) is lithiated by reaction with n-butyllithium. The lithiated PPMS is used to prepare polymers containing functional groups. As an example, a solution of PPMS (MW 260,000), 1.0 g in 20 ml of cyclohexane, was reacted with n-butyllithium, 8.5 mmol, and tetramethylethylenediamine, 8.7 mmol, for 20 hours to obtain a precipitate. The precipitate was dissolved in THF, and CO.sub.2 was blown into the solution. The solution was washed with an aqueous solution of HCl and dropped into methanol to obtain a solid polymer having carboxyl group functionality.
Public/Granted literature
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