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US4873023A Preparation of monoolefinically unsaturated carboxyl-containing versatic esters 失效
制备单烯属不饱和羧基的极性酯

Preparation of monoolefinically unsaturated carboxyl-containing versatic
esters
摘要:
Compounds of the general formulae ##STR1## where R is versatyl and R' is unsubstituted or alkyl-substituted straight-chain alkylene of 4 or 5 carbon atoms can be prepared by reacting the versatic ester of 1,3-dihydroxy-propyl-2 acrylate and/or of 2,3-dihydroxy-propyl-1 acrylate with equimolar amounts of saturated or monoolefinically unsaturated cyclic dicarboxylic anhydrides having 4 or 5 carbon atoms and an oxygen atom in the ring at from 50.degree. to 150.degree. C. in the presence of customary esterification catalysts and can be used as reactive diluents in radiation-curable contact adhesives.
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