发明授权
- 专利标题: Photographic products and processes
- 专利标题(中): 摄影产品和工艺
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申请号: US728210申请日: 1985-04-29
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公开(公告)号: US4631344A公开(公告)日: 1986-12-23
- 发明人: Myron S. Simon , David P. Waller
- 申请人: Myron S. Simon , David P. Waller
- 申请人地址: MA Cambridge
- 专利权人: Polaroid Corporation
- 当前专利权人: Polaroid Corporation
- 当前专利权人地址: MA Cambridge
- 主分类号: C09B1/28
- IPC分类号: C09B1/28 ; C09B1/40 ; G03C8/10 ; C07D277/04 ; C07D277/06
摘要:
Photographic products and processes for the imagewise generation of a dye from a color shifted dye precursor of a preformed image dye, said precursor having at least one ##STR1## group, wherein R is hydrogen, alkyl, provided that the .alpha.-carbon does not have a hydrogen atom attached thereto, aryl such as phenyl or substituted phenyl, e.g. p-nitrophenyl, or heterocyclic such as pyridine; R.sub.1 -R.sub.6 are hydrogen, alkyl, preferably having from 1 to 6 carbon atoms, or aryl; n is 0 or 1; and T is a moiety containing a thiazolidin-2-yl group which upon silver-assisted cleavage of said thiazolidin-2-yl group results in the formation of a ##STR2## group, which may be protonated under the reaction conditions, followed by cleavage of said ##STR3## which cleavage is anchimerically assisted or accelerated by said ##STR4## to provide after protonation, an ##STR5## group in a dye chromophore. In a preferred embodiment the precursor is a substantially colorless compound.
公开/授权文献
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