发明授权
- 专利标题: Making impact resistant polymers
- 专利标题(中): 制造耐冲击聚合物
-
申请号: US226008申请日: 1981-01-19
-
公开(公告)号: US4308354A公开(公告)日: 1981-12-29
- 发明人: Karl A. Jung , Manfred Munzer , Heinz Vetter , Winfried Wunderlich
- 申请人: Karl A. Jung , Manfred Munzer , Heinz Vetter , Winfried Wunderlich
- 申请人地址: DEX Darmstadt
- 专利权人: Rohm GmbH
- 当前专利权人: Rohm GmbH
- 当前专利权人地址: DEX Darmstadt
- 优先权: DEX3002394 19800124
- 主分类号: C08F279/02
- IPC分类号: C08F279/02 ; C08L51/04
摘要:
What is disclosed are a method for making a transparent impact-resistant polymer comprising a rubbery phase of grafted polybutadiene and a hard copolymer phase, which polymer is adaptable to use as a molding material, which method comprises:(1) in a first polymerization stage, dissolving a solid polybutadiene rubber in a monomer mixture comprising (a) methyl methacrylate, (b) styrene, and (c) at least one of methyl acrylate or ethyl acrylate to give a solution containing from 3 to 10 percent by weight of said rubber, and then polymerizing the solution using an initiator promoting graft copolymerization and in the presence ab initio of a chain transfer agent until an amount of said monomer mixture which is one to two times the weight of said polybutadiene rubber introduced is converted, said monomers (a), (b), and (c) being present in said monomer mixture in a ratio by weight of (73.+-.5): (22.+-.2); (5.+-.3) such that the index of refraction of the hard polymer phase produced by the polymerization is equal to that of said polybutadiene, and said initiator being one forming tertiary-butoxy or phenyl free-radicals on decomposition;(2) in a second stage, further polymerizing to a monomer conversion between 25 and 40 percent while stirring to subject the resulting polymer to shear forces producing polymer particles having an average diameter between 0.2 micron and 1.5 microns; and(3) in a third stage, further polymerizing to a monomer conversion greater than 80 percent, and polymers made by such a method.
公开/授权文献
- US5500620A Timing recovery for digital demodulation 公开/授权日:1996-03-19
信息查询