发明授权
- 专利标题: Process for the preparation of semi-rigid polyurethane foam having exceptional shock-absorbing properties and vehicle bumpers thereof
- 专利标题(中): 用于制备具有特殊减震性能的半硬质聚氨酯泡沫的方法及其车辆保险杠
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申请号: US754469申请日: 1976-12-27
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公开(公告)号: US4134610A公开(公告)日: 1979-01-16
- 发明人: Frank W. Lindewall
- 申请人: Frank W. Lindewall
- 申请人地址: SEX Stenungsund
- 专利权人: Berol Kemi AB
- 当前专利权人: Berol Kemi AB
- 当前专利权人地址: SEX Stenungsund
- 优先权: SEX7514661 19751229; SEX7602076 19760213
- 主分类号: C08G18/38
- IPC分类号: C08G18/38 ; C08G18/66 ; B60R19/08 ; B29D27/04 ; C08G18/14
摘要:
A process is provided for producing semi-rigid polyurethane foams having exceptional shock-absorbing properties, even after repeated compression, prepared by the reaction of a polyisocyanate; a polyether polyol having a molecular weight within the range from about 2,000 to about 10,000; from about 1 to about 5% by weight of water per part by weight of polyether polyol; from about 1 to about 6% by weight of urea and/or thiourea per part by weight of polyether polyol; and a cross-linking compound having at least three active hydrogen atoms per molecule that are reactive with isocyanate groups and having a molecular weight below about 1000 in an amount from about 5 to about 25% by weight per part by weight of polyether polyol; the amount of polyisocyanate being selected to give an isocyanate index within the range from about 0.7 to about 1.4.The process provides polyurethane foams that have a cellular structure that remains undamaged under compression as high as 60% at temperatures within the range from about +60.degree. C to about -40.degree. C, and the consequent deformation is less than 1% even after ten compressions of at lest 50% in rapid succession.Accordingly, the invention further provides vehicle bumpers having an impact-receiving layer of this polyurethane foam, and that meet the requirements of FMVSS 215.
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