发明授权
US3974250A Method for reducing crystalline orientation of para-oxybenzoyl polyesters
失效
降低对羟基苯甲酰聚酯的结晶取向的方法
- 专利标题: Method for reducing crystalline orientation of para-oxybenzoyl polyesters
- 专利标题(中): 降低对羟基苯甲酰聚酯的结晶取向的方法
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申请号: US394023申请日: 1973-09-04
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公开(公告)号: US3974250A公开(公告)日: 1976-08-10
- 发明人: Steve G. Cottis , James Economy , Roger S. Storm , Luis C. Wohrer
- 申请人: Steve G. Cottis , James Economy , Roger S. Storm , Luis C. Wohrer
- 申请人地址: NY Niagara Falls
- 专利权人: The Carborundum Company
- 当前专利权人: The Carborundum Company
- 当前专利权人地址: NY Niagara Falls
- 主分类号: B29B15/00
- IPC分类号: B29B15/00 ; B29B9/00 ; B29B13/00 ; B29B13/02 ; B29B13/04 ; C08G63/00 ; C08G63/06 ; C08J3/00 ; C08J5/00 ; B29B3/00
摘要:
Polyesters of para-oxybenzoyl are infusible and very resistant to acids and solvents, thus limiting the means by which such polymers can be fabricated. Such a polyester is made more amorphous, thus improving compression moldability, by subjecting it to a high temperature treatment, followed by a rapid quench. The resulting polymer has reduced crystalline orientation, as evidenced by X-ray diffraction patterns, and molded articles thereof have improved flexural strength, without adversely affecting the modulus. The thermal treatment is carried out on the polymer by heating at a temperature of at least 300.degree.C, and up to just below the decomposition temperature of the polymer, followed by quenching of the hot polymer.
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