发明授权
US3953419A Salts of stilbene-azo and stilbene-azoxy dyes and process for their
preparation
失效
芪 - 偶氮和茋 - 偶氮染料的盐及其制备方法
- 专利标题: Salts of stilbene-azo and stilbene-azoxy dyes and process for their preparation
- 专利标题(中): 芪 - 偶氮和茋 - 偶氮染料的盐及其制备方法
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申请号: US385756申请日: 1973-08-06
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公开(公告)号: US3953419A公开(公告)日: 1976-04-27
- 发明人: Reinhard Pedrazzi
- 申请人: Reinhard Pedrazzi
- 申请人地址: CH Basel
- 专利权人: Sandoz Ltd.
- 当前专利权人: Sandoz Ltd.
- 当前专利权人地址: CH Basel
- 优先权: CH11699/72 19720808; CH4042/72 19720317; CH3477/72 19720309
- 主分类号: C09B56/04
- IPC分类号: C09B56/04 ; C09B69/04 ; D21H21/28 ; C09B27/02
摘要:
Novel salts of stilbene-azo or stilbene-azoxy dyestuffs, in which the cations are selected from tetra-alkylammonium, tetra-alkylammonium in combination with lithium, sodium, potassium or ammonium, and ammonium in combination with lithium, sodium or potassium, have good cold water solubility relative to known salts of such dyes. The preferred dyes have the formula ##SPC1##Wherein1. each R' is independently --SO.sub.3 .sup.-M.sup.+ or --SO.sub.3 .sup.-N.sup.+(R).sub.4,wherein each R is independently alkyl of 1 to 6 carbon atoms or alkyl of 1 to 6 carbon atoms substituted by hydroxy, cyano, halo or phenyl, andEach M.sup.+ is independently hydrogen, lithium, sodium, potassium or ammonium,With the proviso that at least one R' is --SO.sub.3 .sup.-N.sup.+(R).sub.4,2. each R' is --SO.sub.3 .sup.-M.sup.+,wherein each M.sup.+ is lithium, sodium, potassium or ammonium,With the proviso that at least one M.sup.+ is ammonium, or3. each R' is independently --SO.sub.3 .sup.-M.sup.+ or --SO.sub.3 .sup.-N.sup.+(R).sub.4,wherein each R is independently alkyl of 1 to 6 carbon atoms or alkyl of 1 to 6 carbon atoms substituted by hydroxy, cyano or halo, andEach M.sup.+ is ammonium or an alkali metal,With the proviso that at least one R' is --SO.sub.3 .sup.-M.sup.+ wherein M.sup.+ is ammonium.The dyes are useful for producing colored paper by incorporation into paper stock or by application to paper sheet. The dyed paper is fast to light and wet treatments.
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