发明授权
US3860568A Novel polymerization initiator and process for polymerization using the same
失效
新型聚合引发剂和使用该聚合方法的聚合方法
- 专利标题: Novel polymerization initiator and process for polymerization using the same
- 专利标题(中): 新型聚合引发剂和使用该聚合方法的聚合方法
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申请号: US6399970申请日: 1970-06-19
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公开(公告)号: US3860568A公开(公告)日: 1975-01-14
- 发明人: CHABERT HENRI , AIME ROBERT , GIGIOU CLAUDE , RUAUD MICHEL
- 申请人: RHONE POULENC SA
- 专利权人: Rhone Poulenc Sa
- 当前专利权人: Rhone Poulenc Sa
- 优先权: US6399970 1970-06-19; FR61596 1966-05-13; US63735667 1967-05-10
- 主分类号: C08F4/06
- IPC分类号: C08F4/06 ; C08F4/28 ; C08F4/42 ; C08F3/04 ; C08F3/30 ; C08F15/02
摘要:
A process for the polymerization of an olefinic monomer by contacting the monomer with a polymerization initiator having an oxidizing agent, a chelating compound of the metal, in which the metal is still capable of accepting one or more electron pairs from an electron donor and an electron donor in an amount at least equal to that required to complex completely the metal of the chelate compound. With the polymerization initiator, polymerization of the olefinic monomer can be accomplished at low temperatures employing oxidizing agents which are stable at the lower temperatures. Also, the solubility of the initiators allows polymerization by suspension process.
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