发明授权
US3576837A Process for preparatin of bisctrifloro-methyl trioxide and fluoroformyl trifluoromethyl peroxide 失效
二氯三氟甲磺酸和氟代三氟甲磺酸过氧化物的制备方法

Process for preparatin of bisctrifloro-methyl trioxide and fluoroformyl trifluoromethyl peroxide
摘要:
BIS(TRIFLUOROMETHYL) TRIOXIDE AND FLUOROFORMYL TRIFLUOROMETHYL PEROXIDE MAY BE PREPARED BY REACTING CARBONYL FLUORIDE AND DIFLUOROMETHYLENE BIS(OXYFLUORIDE) IN THE PRESENCE OF CSF OR RBF. WITH REACTION TIMES BELOW ABOUT SIX HOURS FLUOROFORMYL TRIFLUOROMETHYL PEROXIDE IS RECOVERED TO THE EXCLUSION OF ANY APPRECIABLE QUANTITY OF BIS(TRIFLUOROMETHYL) TRIOXIDES. WITH REACTION TIMES ABOVE ABOUT 18 HOURS, BIS(TRIFLUOROMETHYL) TRIOXIDE IS RECOVERED TO THE EXCLUSION OF ANY APPRECIABLE QUANTITY OF FLUOROFORMYL TRIFLUOROMETHYL PEROXIDE.
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