A process is provided that can convert the available CO2 stream (from any captured source) and CH4 (or natural gas, or hydrocarbon gas) stream to separated streams of CO and H2. Multiple options exist for utilization. Synthesis gas can be integrated with an existing syngas facility or combined with H2 from an electrolyze to make methanol or FT synthesis to make liquid fuels. When operating the process with separated H2 and CO streams. These can be integrated into different chemical processes and not necessarily mixed together. For example, H2 can be sold as a product, and CO can be used as a feedstock to make chemicals. The present disclosure is a desirable add-on to an industrial facility to process CO2 emission into the value stream.