A failed fuel pin emits cesium into the primary sodium coolant and xenon into the cover gas in a reactor vessel. A pipe containing radioactive liquid sodium accepts flowing primary sodium from the reactor vessel. A radiation detector is positioned adjacent the pipe such that gamma radiation emitted from the pipe can be measured. The pipe may be isolated to increase detection limits by allowing short-lived isotopes to decay. The isotopic ratio of 137Cs/134Cs can be measured, which can be used to determine the burnup of a fuel assembly from within the core, and therefore, the failed fuel assembly can be identified based at least in part on the burnup. Further, mass spectrometry may be used to measure the ratio of a stable and unstable xenon isotope. The identification techniques may be used in conjunction to quickly identify a failed fuel assembly in-situ and during reactor operation.