1,8-SUBSTITUTED CARBAZOLE-BASED PLATINUM COMPLEXES WITH HIGH RADIATION RATE AND APPLICATION THEREOF
摘要:
The present invention provides a high radiation rate platinum complex based on 1,8-substituted carbazole and an application thereof. The luminescent material of the present invention can efficiently control the excited state properties of material molecules by introducing substituents at 1-, 8-position of carbazole, which increases components of metal-to-ligand charge transfer state (MLCT), and improves the intersystem crossing rate of molecules; at the same time, the introduction of substituents at the 1-, 8-position of carbazole can increase the dihedral angle thereof with a pyridine ring, which can improve the rigidity of molecules, effectively reduce the energy consumed by the vibration and rotation of the carbazole ring in the molecules, and reduce non-radiative attenuation. The described factors can jointly increase the radiation rate of material molecules and shorten the lifetime of the excited state.
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