- 专利标题: 1,8-SUBSTITUTED CARBAZOLE-BASED PLATINUM COMPLEXES WITH HIGH RADIATION RATE AND APPLICATION THEREOF
-
申请号: US18555428申请日: 2022-04-22
-
公开(公告)号: US20240239825A1公开(公告)日: 2024-07-18
- 发明人: Guijie LI , Yuanbin SHE , Jianbin ZHENG , Kewei XU
- 申请人: ZHEJIANG UNIVERSITY OF TECHNOLOGY , ZHEJIANG HUAXIAN PHOTOELECTRICITY TECHNOLOGY CO., LTD
- 申请人地址: CN Hangzhou, Zhejiang
- 专利权人: ZHEJIANG UNIVERSITY OF TECHNOLOGY,ZHEJIANG HUAXIAN PHOTOELECTRICITY TECHNOLOGY CO., LTD
- 当前专利权人: ZHEJIANG UNIVERSITY OF TECHNOLOGY,ZHEJIANG HUAXIAN PHOTOELECTRICITY TECHNOLOGY CO., LTD
- 当前专利权人地址: CN Hangzhou, Zhejiang
- 优先权: CN 2110436077.3 2021.04.22
- 国际申请: PCT/CN2022/088329 2022.04.22
- 进入国家日期: 2023-10-13
- 主分类号: C07F15/00
- IPC分类号: C07F15/00 ; C09K11/06 ; H10K50/11 ; H10K50/15 ; H10K50/16 ; H10K50/18 ; H10K85/30
摘要:
The present invention provides a high radiation rate platinum complex based on 1,8-substituted carbazole and an application thereof. The luminescent material of the present invention can efficiently control the excited state properties of material molecules by introducing substituents at 1-, 8-position of carbazole, which increases components of metal-to-ligand charge transfer state (MLCT), and improves the intersystem crossing rate of molecules; at the same time, the introduction of substituents at the 1-, 8-position of carbazole can increase the dihedral angle thereof with a pyridine ring, which can improve the rigidity of molecules, effectively reduce the energy consumed by the vibration and rotation of the carbazole ring in the molecules, and reduce non-radiative attenuation. The described factors can jointly increase the radiation rate of material molecules and shorten the lifetime of the excited state.
信息查询