Invention Publication
- Patent Title: PROCESS FOR PREPARING POLY(ALKYLENE FURANDICARBOXYLATE)
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Application No.: US18141613Application Date: 2023-05-01
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Publication No.: US20230265239A1Publication Date: 2023-08-24
- Inventor: Hari Babu SUNKARA , Paul J. Pigliacampi
- Applicant: Covation Inc.
- Applicant Address: US DE Newark
- Assignee: Covation Inc.
- Current Assignee: Covation Inc.
- Current Assignee Address: US DE Newark
- Main IPC: C08G63/672
- IPC: C08G63/672 ; C08G63/181 ; C08G63/85 ; C08K5/18

Abstract:
A process to prepare poly(alkylene furandicarboxylate) polymer is disclosed herein. In one embodiment, the process comprises a) contacting a mixture comprising furandicarboxylic acid dialkyl ester, a diol comprising ethylene glycol, 1,3-propanediol, 1,4-butanediol, 1,4-cyclohexanedimethanol, or mixtures thereof, and a metal catalyst at a temperature in the range of from about 140° C. to about 220° C. to form prepolymer,
wherein the mole ratio of the furandicarboxylic acid dialkyl ester to the diol is in the range of from 1:1.3 to 1:2.2;
b) performing polycondensation by heating the prepolymer under reduced pressure to a temperature in the range of from about 220° C. to about 260° C. to form poly(alkylene furandicarboxylate) polymer;
wherein the rate of polycondensation in step c) is faster with the anthraquinone compound present than without; and
c) adding at least one anthraquinone compound as disclosed herein; and
wherein the mole ratio of the furandicarboxylic acid dialkyl ester to the diol is in the range of from 1:1.3 to 1:2.2;
b) performing polycondensation by heating the prepolymer under reduced pressure to a temperature in the range of from about 220° C. to about 260° C. to form poly(alkylene furandicarboxylate) polymer;
wherein the rate of polycondensation in step c) is faster with the anthraquinone compound present than without; and
c) adding at least one anthraquinone compound as disclosed herein; and
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