Disclosed is a Chinese knot-like porous fiber core ultra-high birefringence THz optical fiber. The optical fiber comprises a substrate, claddings and fiber cores, wherein the claddings and the fiber cores are arranged in the substrate, and the fiber cores are embedded in the centers of the claddings; and the fiber core comprises a first fiber core region, a second fiber core region and a third fiber core region, the center of the first fiber core region 4 serves as the origin of coordinates, and the first fiber core region 4 is composed of six regular hexagon units with overlapped boundaries in the x-axis direction. In the present disclosure, the fiber core comprises a first fiber core region, a second fiber core region and a third fiber core region, and the three regions jointly form a fiber core region of a Chinese knot-like porous fiber core.