Proposed is a cover structure with a double cover structure and a shooting case of munition having the same. The cover structure with a double cover structure includes: a shooting case main body having an inner space with an open upper side; a cover member seated on the open upper side of the shooting case main body to seal the open upper side; and a cover fixing member coupled to the shooting case main body to fix a position of the cover member, so that the position of the cover member is strongly fixed while simplifying a structure by the double cover structure to increase an internal pressure of the shooting case, thereby increasing a range of munition and maintaining performance of munition.